A sustainable methodology to produce open-cell porous membranes with control on the dense layer thickness

• Published in: Journal of CO2 utilization 2023-08, Vol.74, p.102536, Article 102536
• Main Authors: Cuadra-Rodríguez, D., Soto, C., Carmona, F.J., Tena, A., Palacio, L., Rodríguez-Pérez, M.A., Pinto, J.
• Format: Article
• Language: English
• Subjects: Gas barrier approach; Gas separation; Open-Cell nanostructures; Permeance; Skinless nanocellular foams
• ISSN: 2212-9820; 2212-9839
• DOI: 10.1016/j.jcou.2023.102536

A new approach to produce porous membranes with dense or porous top layer is proposed in this work by employing a solvent-free method. PMMA/MAM formulations were selected as a base material in order to create open-cell or close-cell structures by gas dissolution foaming employing CO2 as a blowing agent. Furthermore, by introducing the gas diffusion barrier approach to CO2 dissolution foaming, it is possible to control the thickness of the dense layer in both edges, obtaining defect-free membranes (i.e., completely dense without pin-holes). The effectiveness of nanocellular polymers as gas separation membranes was evaluated. In this way, the permeability, selectivity, and permeance were correlated to the cellular structure (open or close-cell) as well as to the dense layer thickness. Furthermore, the effective thickness of the selective layer has been calculated from gas permeability measurements, obtaining an accurate control of that parameter from the tunable cellular structure. Therefore, membranes composed of desired selective layer and a porous structure as a mechanical support are produced by a solvent-free methodology. [Display omitted] •A solvent-free methodology to produce porous membranes for gas separation.•Rising the permeance in skinless nanocellular polymers by gas dissolution foaming.•Open-cell structures as mechanical support tuned from foaming parameters.•Well-controlled thickness of the selective layer by gas diffusion barrier approach.•Membranes for a sustainable and circular CO2 cycle (fabrication-gas recovery).