Dry sliding tribological properties of Cu-WS2 self-lubricating composites at 25–500 °C

• Published in: Journal of materials research and technology 2023-05, Vol.24, p.5420-5432
• Main Authors: Yan, Jianhui, Wang, Yi, Guo, YuanJun
• Format: Article
• Language: English
• Subjects: Cu-WS2 composites; Friction and wear; Spark plasma sintering; Wettability
• ISSN: 2238-7854
• DOI: 10.1016/j.jmrt.2023.04.114

Cu-WS2 composites are being used as self-lubricating materials for various engineering applications. The poor wettability between Cu and WS2 is a main obstacle for obtaining high-performance Cu-WS2. In order to improve the wettability, a thin Cu layer was deposited on the surface of the WS2 powder through an electroless plating technology. Cu-WS2 composites were prepared via spark plasma sintering (SPS) using the mix powders of Cu and Cu-WS2. Microstructure, mechanical properties and tribological properties of the Cu-WS2 composites were investigated, and that of the Cu were also comparatively studied. Results show that the WS2 powder coated with Cu (abbreviated as WS2@Cu powder) improves the poor wettability between Cu and WS2 and meanwhile the distribution of WS2. Cu-WS2 composites sintered below 750 °C could reduce the reaction between Cu and WS2 and ensure more WS2 in the composites. Both the coefficient of friction (COF) and the wear rate of the Cu-WS2 are lower than that of the Cu. A lubricant film leads to the excellent tribological properties as the Cu-WS2 composites were tested at 25−200 °C. However, the disappearance of WS2 and the formation of Cu2O cause to the decreasing self-lubricating performances at 300−500 °C. With an increase in the test temperature, the dominant wear mechanisms of the Cu-WS2 composites change from adhesive wear to a mixture of abrasive and oxidation wear, and that of the Cu change from adhesive wear to a mixture of fatigue and oxidation wear.