Optimization of Biodiesel Production from Waste Cooking Oil Using a Green Catalyst Prepared from Glass Waste and Animal Bones

• Published in: Energies (Basel) 2023-03, Vol.16 (5), p.2322
• Main Authors: Asaad, Sara Maen, Inayat, Abrar, Jamil, Farrukh, Ghenai, Chaouki, Shanableh, Abdallah
• Format: Article
• Language: English
• Subjects: Alternative energy sources; biodiesel; Biodiesel fuels; Biofuels; Calcium oxide; Carbon monoxide; Catalysts; Competition; Cooking; Cooking oils; Diesel; Diesel engines; Diesel fuels; Emission standards; Emissions; Energy consumption; Energy industry; Ethical standards; Fast food; Food; Food sources; Fourier transforms; Greenhouse gases; heterogeneous catalyst; Infrared spectroscopy; Lime; Oil wastes; Oils & fats; Oils and fats, Edible; Optimization; Production processes; Raw materials; Reaction time; Renewable resources; Response surface methodology; Scanning electron microscopy; Shells; Silica; Silicon dioxide; Transesterification; Viscosity; waste cooking oil; Waste materials; Wastes; X-ray diffraction
• ISSN: 1996-1073; 1996-1073
• DOI: 10.3390/en16052322

Biodiesel as a fuel has been shown to positively impact the environment; replacing or reducing the dependence on fossil fuels while providing a viable alternative. The use of waste oils, such as non-edible or used oils, can reduce competition with food, loss of resources, and the resulting higher prices. In this study, biodiesel was obtained by a transesterification reaction using used cooking oil from fast-food restaurants as the feedstock and catalysts from waste glass and animal bones as the silica and calcium oxide sources, respectively. Utilizing waste or non-edible oils for the production of biodiesel can lessen the competition with food sources while achieving environmental and ethical biofuel standards. Additionally, employing readily available waste oils and catalysts prepared from waste material is an economical and low-cost process compared to the use of conventional expensive feedstock and catalyst. The catalyst characterization for the prepared CaO–SiO2 catalyst was performed using X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FT-IR). The reaction was optimized using the response surface methodology (RSM) with central composite design (CCD) by varying three parameters: methanol-to-oil ratio, catalyst weight fraction (wt%), and reaction time. The highest biodiesel yield obtained using Design Expert software was 92.3419% at the optimum conditions of a 14.83:1 methanol-to-oil molar ratio, 3.11 wt% catalyst, and 143 min reaction time. This proved that waste cooking oil with CaO–SiO2 catalyst could be used in the transesterification process to produce a high yield of biodiesel, which was shown in the results obtained from the experimental runs.