Comparative Properties of K/NaX and K/NaY from Ultrasound-Assisted Impregnation and Performance in Transesterification of Palm Oil

• Published in: ACS omega 2022-03, Vol.7 (11), p.9130-9141
• Main Authors: Kosawatthanakun, Siriporn, Pansakdanon, Chaianun, Sosa, Narongrit, Chanlek, Narong, Roessner, Frank, Prayoonpokarach, Sanchai, Wittayakun, Jatuporn
• Format: Article
• Language: English
• ISSN: 2470-1343; 2470-1343
• DOI: 10.1021/acsomega.1c04912

This work aims to compare physicochemical properties and catalytic performance of potassium supported on zeolite NaX and NaY (K/NaX and K/NaY, respectively) prepared by ultrasound-assisted impregnation from potassium acetate buffer precursor. Calcination converts the potassium precursor to carbonate, which occupies the zeolite cavities and disperses on the external surface. Both calcined samples show a decrease in zeolite phases, BET surface areas, and pore volumes. With the smaller changes, K/NaX is more stable than K/NaY. Moreover, K/NaX has higher basicity than K/NaY and is more active in the decomposition of 2-methylbut-3-yn-2-ol (MBOH), producing dominant products from basic sites. Both K/NaX and K/NaY are active in the transesterification of palm oil, producing more than 94% of the biodiesel yields in the first run. However, the yields drop in the second run because of the leaching of potassium species into glycerol and biodiesel products. The spent K/NaX has a similar phase to the fresh one, whereas the spent K/NaY shows more structure collapse. With better structural stability, less potassium leaching, and less decline in biodiesel yields in the second run, K/NaX is a better catalyst than K/NaY.