Engineering Sodium Metal Anode with Sodiophilic Bismuthide Penetration for Dendrite-Free and High-Rate Sodium-Ion Battery

• Published in: Engineering (Beijing, China) China), 2022-04, Vol.11 (4), p.87-94
• Main Authors: Zhao, Wanyu, Guo, Min, Zuo, Zhijun, Zhao, Xiaoli, Dou, Huanglin, Zhang, Yijie, Li, Shiying, Wu, Zichen, Shi, Yayun, Ma, Zifeng, Yang, Xiaowei
• Format: Article
• Language: English
• Subjects: Compact electrodeposition; Dendrite-free; Ion diffusion barrier; Sodiophilic bismuthide; Sodium metal anode
• ISSN: 2095-8099
• DOI: 10.1016/j.eng.2021.08.028

Sodium (Na) metal batteries with a high volumetric energy density that can be operated at high rates are highly desirable. However, an uneven Na-ion migration in bulk Na anodes leads to localized deposition/dissolution of sodium during high-rate plating/stripping behaviors, followed by severe dendrite growth and loose stacking. Herein, we engineer the Na hybrid anode with sodiophilic Na3Bi-penetration to develop the abundant phase-boundary ionic transport channels. Compared to intrinsic Na, the reduced adsorption energy and ion-diffusion barrier on Na3Bi ensure even Na+ nucleation and rapid Na+ migration within the hybrid electrode, leading to uniform deposition and dissolution at high current densities. Furthermore, the bismuthide enables compact Na deposition within the sodiophilic framework during cycling, thus favoring a high volumetric capacity. Consequently, the obtained anode was endowed with a high current density (up to 5 mA∙cm−2), high areal capacity (up to 5 mA∙h∙cm−2), and long-term cycling stability (up to 2800 h at 2 mA∙cm−2).