Study of mixed ternary transition metal ferrites as potential electrodes for supercapacitor applications

• Published in: Results in physics 2017, Vol.7, p.345-353
• Main Authors: Bhujun, Bhamini, Tan, Michelle T.T., Shanmugam, Anandan S.
• Format: Article
• Language: English
• Subjects: Asymmetric supercapacitor; Cyclic voltammetry; Mixed ternary transition metal ferrite (MTTMF); Nanocomposites; Sol–gel
• ISSN: 2211-3797; 2211-3797
• DOI: 10.1016/j.rinp.2016.04.010

•Synthesis of MTTMF nanocomposites via a facile sol-gel method.•XRD confirms the spinel ferrite peak in the synthesised nanomaterials SEM micrographs demonstrate a highly porous structure.•A supercapacitive performance of 221 Fg−1 is achieved with CuCoF. Nanocrystallites of three mixed ternary transition metal ferrite (MTTMF) were prepared by a facile sol–gel method and adopted as electrode material for supercapacitors. The phase development of the samples was determined using Fourier transform infrared (FT-IR) and thermal gravimetric analysis (TG). X-ray diffraction (XRD) analysis revealed the formation of a single-phase spinel ferrite in CuCoFe2O4 (CuCoF), NiCoFe2O4 (NiCoF) and NiCuFe2O4 (NiCuF). The surface characteristics and elemental composition of the nanocomposites have been studied by means of field emission scanning electron microscopy (FESEM), as well as energy dispersive spectroscopy (EDS). The electrochemical performance of the nanomaterials was evaluated using a two-electrode configuration by cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic technique in 1M KOH electrolyte and was found to be in the order of: CuCoF>NiCoF>NiCuF. A maximum specific capacitance of 221Fg−1 was obtained with CuCoF at a scan rate of 5mVs−1. In addition to an excellent cycling stability, an energy density of 7.9kWkg−1 was obtained at a current density of 1Ag−1. The high electrochemical performance of the MTTMF nanocomposites obtained indicates that these materials are promising electrodes for supercapacitors.