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Facile Preparation of Cu2O Nanoparticles and Reduced Graphene Oxide Nanocomposite for Electrochemical Sensing of Rhodamine B
In this paper, the preparation, characterization, and electrochemical application of Cu2O nanoparticles and an electrochemical reduced graphene oxide nanohybrid modified glassy carbon electrode (denoted as Cu2O NPs‒ERGO/GCE) are described. This modified electrode was used as an electrochemical senso...
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Published in: | Nanomaterials (Basel, Switzerland) Switzerland), 2019-07, Vol.9 (7), p.958 |
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description | In this paper, the preparation, characterization, and electrochemical application of Cu2O nanoparticles and an electrochemical reduced graphene oxide nanohybrid modified glassy carbon electrode (denoted as Cu2O NPs‒ERGO/GCE) are described. This modified electrode was used as an electrochemical sensor for the catalytic oxidation of rhodamine B (RhB), and it exhibited an excellent electrochemical performance for RhB. The oxidation potential of RhB was decreased greatly, and the sensitivity to detect RhB was improved significantly. Under optimum conditions, a linear dynamic range of 0.01–20.0 μM and a low detection limit of 0.006 μM were obtained with the Cu2O NPs‒ERGO/GCE by using second‒order derivative linear sweep voltammetry. In addition, the selectivity of the prepared modified electrode was analyzed for the determination of RhB. The practical application of this sensor was investigated for the determination of RhB in food samples, and satisfactory results were obtained. |
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This modified electrode was used as an electrochemical sensor for the catalytic oxidation of rhodamine B (RhB), and it exhibited an excellent electrochemical performance for RhB. The oxidation potential of RhB was decreased greatly, and the sensitivity to detect RhB was improved significantly. Under optimum conditions, a linear dynamic range of 0.01–20.0 μM and a low detection limit of 0.006 μM were obtained with the Cu2O NPs‒ERGO/GCE by using second‒order derivative linear sweep voltammetry. In addition, the selectivity of the prepared modified electrode was analyzed for the determination of RhB. The practical application of this sensor was investigated for the determination of RhB in food samples, and satisfactory results were obtained.</description><identifier>ISSN: 2079-4991</identifier><identifier>EISSN: 2079-4991</identifier><identifier>DOI: 10.3390/nano9070958</identifier><identifier>PMID: 31262035</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Carbon ; Chemical sensors ; Copper oxides ; Cost control ; Cu2O nanoparticles ; Dopamine ; electroanalysis ; Electrochemical analysis ; Electrochemistry ; Electrodes ; Glassy carbon ; Glucose ; Graphene ; Hydrogen peroxide ; Laboratories ; Methods ; Nanocomposites ; Nanoparticles ; Oxidation ; reduced graphene oxide ; Rhodamine ; rhodamine B ; Selectivity ; Sensors ; Voltammetry</subject><ispartof>Nanomaterials (Basel, Switzerland), 2019-07, Vol.9 (7), p.958</ispartof><rights>2019. This work is licensed under https://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2019 by the authors. 2019</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c452t-ff32cfe5aa1da92a125613dd4ebc1b8cf9c462c5ecb845fce41c2d5a02ee81283</citedby><cites>FETCH-LOGICAL-c452t-ff32cfe5aa1da92a125613dd4ebc1b8cf9c462c5ecb845fce41c2d5a02ee81283</cites><orcidid>0000-0002-4577-5892 ; 0000-0001-9458-469X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/2302201752/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2302201752?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,25752,27923,27924,37011,37012,44589,53790,53792,74897</link.rule.ids></links><search><creatorcontrib>He, Quanguo</creatorcontrib><creatorcontrib>Liu, Jun</creatorcontrib><creatorcontrib>Tian, Yaling</creatorcontrib><creatorcontrib>Wu, Yiyong</creatorcontrib><creatorcontrib>Magesa, Felista</creatorcontrib><creatorcontrib>Deng, Peihong</creatorcontrib><creatorcontrib>Li, Guangli</creatorcontrib><title>Facile Preparation of Cu2O Nanoparticles and Reduced Graphene Oxide Nanocomposite for Electrochemical Sensing of Rhodamine B</title><title>Nanomaterials (Basel, Switzerland)</title><description>In this paper, the preparation, characterization, and electrochemical application of Cu2O nanoparticles and an electrochemical reduced graphene oxide nanohybrid modified glassy carbon electrode (denoted as Cu2O NPs‒ERGO/GCE) are described. This modified electrode was used as an electrochemical sensor for the catalytic oxidation of rhodamine B (RhB), and it exhibited an excellent electrochemical performance for RhB. The oxidation potential of RhB was decreased greatly, and the sensitivity to detect RhB was improved significantly. Under optimum conditions, a linear dynamic range of 0.01–20.0 μM and a low detection limit of 0.006 μM were obtained with the Cu2O NPs‒ERGO/GCE by using second‒order derivative linear sweep voltammetry. In addition, the selectivity of the prepared modified electrode was analyzed for the determination of RhB. The practical application of this sensor was investigated for the determination of RhB in food samples, and satisfactory results were obtained.</description><subject>Carbon</subject><subject>Chemical sensors</subject><subject>Copper oxides</subject><subject>Cost control</subject><subject>Cu2O nanoparticles</subject><subject>Dopamine</subject><subject>electroanalysis</subject><subject>Electrochemical analysis</subject><subject>Electrochemistry</subject><subject>Electrodes</subject><subject>Glassy carbon</subject><subject>Glucose</subject><subject>Graphene</subject><subject>Hydrogen peroxide</subject><subject>Laboratories</subject><subject>Methods</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Oxidation</subject><subject>reduced graphene oxide</subject><subject>Rhodamine</subject><subject>rhodamine 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Preparation of Cu2O Nanoparticles and Reduced Graphene Oxide Nanocomposite for Electrochemical Sensing of Rhodamine B</title><author>He, Quanguo ; Liu, Jun ; Tian, Yaling ; Wu, Yiyong ; Magesa, Felista ; Deng, Peihong ; Li, Guangli</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c452t-ff32cfe5aa1da92a125613dd4ebc1b8cf9c462c5ecb845fce41c2d5a02ee81283</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Carbon</topic><topic>Chemical sensors</topic><topic>Copper oxides</topic><topic>Cost control</topic><topic>Cu2O nanoparticles</topic><topic>Dopamine</topic><topic>electroanalysis</topic><topic>Electrochemical analysis</topic><topic>Electrochemistry</topic><topic>Electrodes</topic><topic>Glassy carbon</topic><topic>Glucose</topic><topic>Graphene</topic><topic>Hydrogen peroxide</topic><topic>Laboratories</topic><topic>Methods</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Oxidation</topic><topic>reduced graphene oxide</topic><topic>Rhodamine</topic><topic>rhodamine B</topic><topic>Selectivity</topic><topic>Sensors</topic><topic>Voltammetry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>He, Quanguo</creatorcontrib><creatorcontrib>Liu, Jun</creatorcontrib><creatorcontrib>Tian, Yaling</creatorcontrib><creatorcontrib>Wu, Yiyong</creatorcontrib><creatorcontrib>Magesa, Felista</creatorcontrib><creatorcontrib>Deng, Peihong</creatorcontrib><creatorcontrib>Li, Guangli</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion 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Guangli</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Facile Preparation of Cu2O Nanoparticles and Reduced Graphene Oxide Nanocomposite for Electrochemical Sensing of Rhodamine B</atitle><jtitle>Nanomaterials (Basel, Switzerland)</jtitle><date>2019-07-01</date><risdate>2019</risdate><volume>9</volume><issue>7</issue><spage>958</spage><pages>958-</pages><issn>2079-4991</issn><eissn>2079-4991</eissn><abstract>In this paper, the preparation, characterization, and electrochemical application of Cu2O nanoparticles and an electrochemical reduced graphene oxide nanohybrid modified glassy carbon electrode (denoted as Cu2O NPs‒ERGO/GCE) are described. This modified electrode was used as an electrochemical sensor for the catalytic oxidation of rhodamine B (RhB), and it exhibited an excellent electrochemical performance for RhB. The oxidation potential of RhB was decreased greatly, and the sensitivity to detect RhB was improved significantly. Under optimum conditions, a linear dynamic range of 0.01–20.0 μM and a low detection limit of 0.006 μM were obtained with the Cu2O NPs‒ERGO/GCE by using second‒order derivative linear sweep voltammetry. In addition, the selectivity of the prepared modified electrode was analyzed for the determination of RhB. The practical application of this sensor was investigated for the determination of RhB in food samples, and satisfactory results were obtained.</abstract><cop>Basel</cop><pub>MDPI AG</pub><pmid>31262035</pmid><doi>10.3390/nano9070958</doi><orcidid>https://orcid.org/0000-0002-4577-5892</orcidid><orcidid>https://orcid.org/0000-0001-9458-469X</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Carbon Chemical sensors Copper oxides Cost control Cu2O nanoparticles Dopamine electroanalysis Electrochemical analysis Electrochemistry Electrodes Glassy carbon Glucose Graphene Hydrogen peroxide Laboratories Methods Nanocomposites Nanoparticles Oxidation reduced graphene oxide Rhodamine rhodamine B Selectivity Sensors Voltammetry |
title | Facile Preparation of Cu2O Nanoparticles and Reduced Graphene Oxide Nanocomposite for Electrochemical Sensing of Rhodamine B |
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