Rheological and Electrochemical Properties of Biodegradable Chia Mucilage Gel Electrolyte Applied to Supercapacitor

• Published in: Batteries (Basel) 2023-10, Vol.9 (10), p.512
• Main Authors: Kim, Inkyum, San, Su Thiri, Mendhe, Avinash C., Dhas, Suprimkumar D., Jeon, Seung-Bae, Kim, Daewon
• Format: Article
• Language: English
• Subjects: Activated carbon; Analysis; biodegradability; Capacitance; Carbohydrates; Charge transfer; chia seed mucilage; Composition; Design and construction; Discharge; Electrochemical analysis; Electrochemical impedance spectroscopy; Electrochemistry; Electrodes; Electrolytes; Electrons; Energy storage; Flexible components; gel electrolyte; Hydrogels; Materials; Methods; Molten salt electrolytes; Polymers; Portable equipment; Rheological properties; Rheology; Seeds; Shear thinning (liquids); Solid electrolytes; Spectrum analysis; supercapacitor; Supercapacitors; Thermal stability; Ultracapacitors; Voltammetry
• ISSN: 2313-0105; 2313-0105
• DOI: 10.3390/batteries9100512

The flexible energy storage device of high demand in wearable and portable electronics. Flexible supercapacitors have benefits over flexible batteries, and their development relies on the use of flexible components. Gel polymer electrolytes have the merits of liquid and solid electrolytes and are used in flexible devices. In this study, a gel derived from chia seed was used as a flexible electrolyte material, and its rheological, thermal, and electrochemical properties were investigated. High thermal stability and shear thinning behavior were observed via the electrolyte state of the chia mucilage gel. Compared to the conventional salt electrolyte, the chia mucilage gel electrolyte-based supercapacitor exhibited a more rectangular cyclic voltammetry (CV) curve, longer discharging time in galvanostatic charge–discharge (GCD) analysis, and low charge transfer resistance in electrochemical impedance spectroscopy (EIS). The maximum specific capacitance of 7.77 F g−1 and power density of 287.7 W kg−1 were measured, and stable capacitance retention of 94% was achieved after 10,000 cycles of charge/discharge with harsh input conditions. The biodegradability was also confirmed by the degraded mucilage film in soil after 30 days. The plant-driven chia mucilage gel electrolyte can facilitate the realization of flexible supercapacitors for the energy storage devices of the future.