Operando monitoring of dendrite formation in lithium metal batteries via ultrasensitive tilted fiber Bragg grating sensors

• Published in: Light, science & applications science & applications, 2024-01, Vol.13 (1), p.24-14, Article 24
• Main Authors: Han, Xile, Zhong, Hai, Li, Kaiwei, Xue, Xiaobin, Wu, Wen, Hu, Nan, Lu, Xihong, Huang, Jiaqiang, Xiao, Gaozhi, Mai, Yaohua, Guo, Tuan
• Format: Article
• Language: English
• Subjects: 639/624/1075/1083; 639/624/1075/187; 639/624/1107/510; Dendrites; Electrochemistry; Electrodes; Electrolytes; Lasers; Lithium; Mass transport; Microwaves; Optical and Electronic Materials; Optical Devices; Optics; Photonics; Physics; Physics and Astronomy; RF and Optical Engineering; Sensors
• ISSN: 2047-7538; 2095-5545; 2047-7538
• DOI: 10.1038/s41377-023-01346-5

Lithium (Li) dendrite growth significantly deteriorates the performance and shortens the operation life of lithium metal batteries. Capturing the intricate dynamics of surface localized and rapid mass transport at the electrolyte–electrode interface of lithium metal is essential for the understanding of the dendrite growth process, and the evaluation of the solutions mitigating the dendrite growth issue. Here we demonstrate an approach based on an ultrasensitive tilted fiber Bragg grating (TFBG) sensor which is inserted close to the electrode surface in a working lithium metal battery, without disturbing its operation. Thanks to the superfine optical resonances of the TFBG, in situ and rapid monitoring of mass transport kinetics and lithium dendrite growth at the nanoscale interface of lithium anodes have been achieved. Reliable correlations between the performance of different natural/artificial solid electrolyte interphases (SEIs) and the time-resolved optical responses have been observed and quantified, enabling us to link the nanoscale ion and SEI behavior with the macroscopic battery performance. This new operando tool will provide additional capabilities for parametrization of the batteries’ electrochemistry and help identify the optimal interphases of lithium metal batteries to enhance battery performance and its safety. Operando monitoring of mass transport kinetics and lithium dendrite growth in lithium metal batteries and parametrization of the batteries’ electrochemistry and safety have been achieved using optical fiber sensors.