Oxygen vacancy-rich nanoporous Cu-CoOx/CC hybrid catalyst for controllable electrocatalytic reduction of nitrate

• Published in: Separation and purification technology 2023-12, Vol.326, Article 124815
• Main Authors: Yang, Shuqin, Wang, Xiuli, Jin, Dongyu, Li, Weiman, Gao, Zan, Liu, Cuicui, Wang, Jingyi, Song, Laizhou
• Format: Article
• Language: English
• Subjects: Cu-CoOx/CC catalyst; Electrocatalytic reduction; Interfacial synergy effect; Nitrate removal; Oxygen vacancy
• ISSN: 1383-5866; 1873-3794
• DOI: 10.1016/j.seppur.2023.124815

[Display omitted] •A novel Cu-CoOx/CC is constructed by hydrothermal-calcination-reduction strategy.•Multi-interface structured Cu-CoOx/CC possesses abundant oxygen vacancies.•Cu-CoOx/CC hybrid is competent for electroreduction conversion of NO3–-N.•Synergistic effect of Cu and CoOx is crucial for the formation of N2. Electrocatalytic nitrate reduction (ENR) to N2 is a promising approach to eliminate nitrate (NO3–-N) for solving the eutrophication of water bodies, but it still faces the significant challenge of exploiting efficient electrocatalysts. Herein, a three-dimensional self-supporting Cu-CoOx/CC hybrid was fabricated based on the oxygen vacancy-rich and interfacial engineering strategies for the purpose of the effective electrochemical conversion of NO3–-N to N2. The fabricated hybrid catalyst possessed a unique structure of nanoporous, oxygen vacancy-rich and multi-interface. More importantly, it was effectively competent for the selective reduction of NO3–-N to N2. Under the optimized conditions (initial NO3–-N concentration: 50 mg/L; pH: 7.0; current density: 20 mA cm−2), the Cu-CoOx/CC exhibited 92.3% NO3–-N removal efficiency and 57.8 % N2 selectivity after 3 h electrolysis treatment. Moreover, due to the synergistic coupling of Cu and CoOx, the electrocatalytic NO3–-N reduction performances and expected intermediates can be regulated. This work could provide a valuable guidance for the synthesis of highly active and selective ERN hybrid electrocatalysts and the pollution control of water eutrophication.