Radiometric detector options to aid in DOE high activity waste tank in situ characterization efforts

• Published in: Journal of radioanalytical and nuclear chemistry 2013-05, Vol.296 (2), p.1017-1023
• Main Authors: DiPrete, David P., DiPrete, Cecilia C., McMahon, Kieran J., Malek, Mira A., Couture, Alexander H., Pak, Donald J.
• Format: Article
• Language: English
• Subjects: Analysis; Chemistry; Chemistry and Materials Science; Design and construction; Detectors; Diagnostic Radiology; Hadrons; Heavy Ions; Inorganic Chemistry; Nuclear Chemistry; Nuclear Physics; Nuclear radiation; Physical Chemistry; Radioactive pollution; Radioactive waste disposal; Radioactive wastes
• ISSN: 0236-5731; 1588-2780
• DOI: 10.1007/s10967-012-2185-0

Radioactive waste cleanup and subsequent closure of waste storage tanks is currently underway at the Savannah river site, prompting the need to characterize the residual contents (heels) of the tanks. Occasionally, results from laboratory analyses indicate alternative sub-sampling strategies are needed, resulting in repetitive efforts to sample and analyze tank bottoms. The development of a system for in situ tank analyses using a radiometric probe, which could be lowered into a waste tank, could aid in identifying waste structures on tank bottoms requiring further sampling and characterization. Ideally, the probe would provide information for determining which structures were higher in concentrations of actinides and fission products characteristic of DOE high level waste (HLW) heels. Although only a limited set of isotopes can be measured directly without extensive radiochemical separations, the low-energy photon spectra of HLW do offer some intriguing possibilities for characterization using a radiometric probe. One possibility for obtaining a low-energy photon spectrum in the presence of high levels of interfering radiation would be to design a probe primarily based upon recently developed technology from Amptek Inc. Such a detector would be relatively insensitive to the high photon background, which would paralyze conventional gamma probes (i.e. sodium iodide) subjected to the same radiological conditions. The prototype detector is capable of successfully obtaining high resolution measurements at very high count rates (in excess of 500,000 counts per second). An overview of measurements obtained from various HLW samples using the prototype Amptek detector, as well as some additional detector technologies, which could enhance this prototype, will be discussed.