Bryophyte-Bioinspired Nanoporous AAO/C/MgO Composite for Enhanced CO[sub.2] Capture: The Role of MgO

• Published in: Nanomaterials (Basel, Switzerland) Switzerland), 2024-04, Vol.14 (8)
• Main Authors: Cortés-Valadez, Paulina Jaqueline, Baños-López, Esperanza, Hernández-Rodríguez, Yazmín Mariela, Cigarroa-Mayorga, Oscar Eduardo
• Format: Article
• Language: English
• Subjects: Aluminum oxide; Analysis; Bryophytes; Carbon; Chemical properties; Chemical synthesis; Influence; Magnesium oxide; Mechanical properties; Methods; Nanoparticles; Photoelectron spectroscopy; Scanning microscopy; X-ray spectroscopy
• ISSN: 2079-4991; 2079-4991
• DOI: 10.3390/nano14080658

A composite material composed of anodized aluminum oxide (AAO), carbon (C), and magnesium oxide (MgO) was developed for CO[sub.2] capture applications. Inspired by the bryophyte organism, the AAO/C/MgO composite mirrors two primary features of these species—(1) morphological characteristics and (2) elemental composition—specifically carbon, oxygen, and magnesium. The synthesis process involved two sequential steps: electroanodization of aluminum foil followed by a hydrothermal method using a mixture of glucose and magnesium chloride (MgCl[sub.2] ). The concentration of MgCl[sub.2] was systematically varied as the sole experimental variable across five levels—1 mM, 2 mM, 3 mM, 4 mM, and 5 mM—to investigate the impact of MgO formation on the samples’ chemical and physical properties, and consequently, their CO[sub.2] capture efficiency. Thus, scanning electron microscopy analysis revealed the AAO substrate’s porous structure, with pore diameters measuring 250 ± 30 nm. The growth of MgO on the AAO substrate resulted in spherical structures, whose diameter expanded from 15 nm ± 3 nm to 1000 nm ± 250 nm with increasing MgCl[sub.2] concentration from the minor to major concentrations explored, respectively. X-ray photoelectron spectroscopy (XPS) analysis indicated that carbon serves as a linking agent between AAO and MgO within the composite. Notably, the composite synthesized with a 4 mM MgCl[sub.2] concentration exhibited the highest CO[sub.2] capture efficiency, as determined by UV-Vis absorbance studies using a sodium carbonate solution as the CO[sub.2] source. This efficiency was quantified with a ‘k’ constant of 0.10531, significantly higher than those of other studied samples. The superior performance of the 4 mM MgCl[sub.2] sample in CO[sub.2] capture is likely due to the optimal density of MgO structures formed on the sample’s surface, enhancing its adsorptive capabilities as suggested by the XPS results.