Crystallization and second harmonic generation in thermally poled niobium borophosphate glasses

• Published in: Journal of solid state chemistry 2005-06, Vol.178 (6), p.1888-1897
• Main Authors: Malakho, Artem, Dussauze, Marc, Fargin, Evelyne, Lazoryak, Bogdan, Rodriguez, Vincent, Adamietz, Frederic
• Format: Article
• Language: English
• Subjects: Borophosphate glasses; Chemical Sciences; Glass–ceramic composites; Material chemistry; Niobium glasses; Optical nonlinearity; Second harmonic generation; Thermal poling
• ISSN: 0022-4596; 1095-726X
• DOI: 10.1016/j.jssc.2005.03.035

Crystallization of glasses with compositions (1− x)(0.95 NaPO 3+0.05 Na 2B 4O 7)+ xNb 2O 5, x = 0.4 , 0.43, 0.45, 0.48 was investigated by differential scanning calorimetry and X-ray powder diffraction. Crystallization of two phases was observed in the glasses with x = 0.43 – 0.48 . First phase is a sodium niobate with the structure of tetragonal tungsten bronze ( T c ∼ 720 – 760 ° C ) and second phase is Na 4Nb 8P 4O 32 ( T c ∼ 830 – 850 ° C ). The crystallization of sodium niobate is correlated with increasing of nonlinear optical efficiency reported for thermally poled glasses with x > 0.4 . The results of Raman spectroscopy show the formation of three-dimensional (3D) niobium oxide framework in the glasses with increase of niobium concentration. This framework is supposed to have tetragonal tungsten bronze structure and to be responsible for nonlinear optical properties of the glass. Second harmonic generation signals of as prepared and crystallized glass after thermal poling are compared. The nucleation and crystallization do not improve the NLO properties of the glasses under study. Optical transmission spectra for as-prepared NBP48 glass, sample of NBP48 glass heated at 680 °C for 100 h (dashed line) and crystallized samples obtained by heating of the same glass for 5 h at the temperatures 720–740 °C.