Loading…
Adsorption properties and inhibition of mild steel corrosion in hydrochloric solution by some newly synthesized diamine derivatives: Experimental and theoretical investigations
New diamine derivatives, namely 2-[{2-[bis-(2-hydroxyethyl)amino]ethyl}(2-hydroxyethyl)amino]ethanol (DAME) and 2-[{2-[bis-(2-hydroxyethyl)amino]ethyl}(2-hydroxyethyl)amino]propanol (DAMP) were synthesised and their inhibitive action against the corrosion of mild steel in 1 M HCl solution were inves...
Saved in:
Published in: | Corrosion science 2010-09, Vol.52 (9), p.3042-3051 |
---|---|
Main Authors: | , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Summary: | New diamine derivatives, namely 2-[{2-[bis-(2-hydroxyethyl)amino]ethyl}(2-hydroxyethyl)amino]ethanol (DAME) and 2-[{2-[bis-(2-hydroxyethyl)amino]ethyl}(2-hydroxyethyl)amino]propanol (DAMP) were synthesised and their inhibitive action against the corrosion of mild steel in 1
M HCl solution were investigated at 308
K. The detailed study of DAME is given using gravimetric measurements and polarization curves method. Results show that DAME is a good inhibitor and inhibition efficiency reaches 91.7% at 10
−3
M. Tafel polarization study revealed that DAME acts as a mixed-type inhibitor. The inhibitor adsorption process in mild steel/DAME/hydrochloric acid system was studied at different temperatures (308–353
K) by means of weight loss measurements. The adsorption of DAME on steel surface obeyed Langmuir’s adsorption isotherm. The kinetic and thermodynamic parameters for mild steel corrosion and inhibitor adsorption, respectively, were determined and discussed. The comparative study of inhibitive performance of the two diamine derivatives revealed that DAME is more effective than DAMP. Quantitative Structure–Activity Relationship (QSAR) approach has been conducted in attempt to correlate the corrosion inhibition properties of these diamine derivatives with their calculated quantum chemical parameters. |
---|---|
ISSN: | 0010-938X 1879-0496 |
DOI: | 10.1016/j.corsci.2010.05.024 |