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Selective hydrogenation of 1,3-butadiene over Pd and Pd–Sn catalysts supported on different phases of alumina

The gas phase selective hydrogenation of 1,3-butadiene was studied over Pd and Pd–Sn supported on mixed phase θ/α-(MA) and pure α-alumina (AA). The catalysts were characterized by XRD, XPS, TEM, and FTIR spectroscopy of adsorbed CO. A remarkable improvement in terms of activity and selectivity in th...

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Published in:	Catalysis today 2011, Vol.164 (1), p.28-33
Main Authors:	Pattamakomsan, Kanda, Ehret, Eric, Morfin, Franck, Gélin, Patrick, Jugnet, Yvette, Prakash, Swamny, Bertolini, Jean Claude, Panpranot, Joongjai, Aires, Francisco José Cadete Santos
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Language:	English
Subjects:	1,3-Butadiene hydrogenation aluminum oxide Catalysis catalysts catalytic activity Chemical Sciences Chemistry Environment and Society Environmental Sciences Exact sciences and technology Fourier transform infrared spectroscopy General and physical chemistry hydrogenation isomerization Mixed phase alumina Pd/Al 2O 3 Pd–Sn/Al 2O 3 Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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cited_by	cdi_FETCH-LOGICAL-c431t-2ed6cc7f5b9d1a505d146f766c7682113ae53efc6f82bc2776d399fa608b22c83
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description	The gas phase selective hydrogenation of 1,3-butadiene was studied over Pd and Pd–Sn supported on mixed phase θ/α-(MA) and pure α-alumina (AA). The catalysts were characterized by XRD, XPS, TEM, and FTIR spectroscopy of adsorbed CO. A remarkable improvement in terms of activity and selectivity in the selective hydrogenation of 1,3-butadiene was achieved over Pd–Sn on the mixed phase alumina support in which butane formation and isomerization of 1-butene were suppressed. Nevertheless, Pd–Sn/AA showed much lower activity than Pd–Sn/MA due to lower metal dispersion.
doi_str_mv	10.1016/j.cattod.2010.10.013
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Nevertheless, Pd–Sn/AA showed much lower activity than Pd–Sn/MA due to lower metal dispersion.</description><subject>1,3-Butadiene hydrogenation</subject><subject>aluminum oxide</subject><subject>Catalysis</subject><subject>catalysts</subject><subject>catalytic activity</subject><subject>Chemical Sciences</subject><subject>Chemistry</subject><subject>Environment and Society</subject><subject>Environmental Sciences</subject><subject>Exact sciences and technology</subject><subject>Fourier transform infrared spectroscopy</subject><subject>General and physical chemistry</subject><subject>hydrogenation</subject><subject>isomerization</subject><subject>Mixed phase alumina</subject><subject>Pd/Al 2O 3</subject><subject>Pd–Sn/Al 2O 3</subject><subject>Theory of reactions, general kinetics. Catalysis. 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subjects	1,3-Butadiene hydrogenation aluminum oxide Catalysis catalysts catalytic activity Chemical Sciences Chemistry Environment and Society Environmental Sciences Exact sciences and technology Fourier transform infrared spectroscopy General and physical chemistry hydrogenation isomerization Mixed phase alumina Pd/Al 2O 3 Pd–Sn/Al 2O 3 Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
title	Selective hydrogenation of 1,3-butadiene over Pd and Pd–Sn catalysts supported on different phases of alumina
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