Study of the first paramagnetic to ferromagnetic transition in as prepared samples of Mn–Fe–P–Si magnetocaloric compounds prepared by different synthesis routes

• Published in: Journal of magnetism and magnetic materials 2016-02, Vol.400, p.333-338
• Main Authors: Bartok, A., Kustov, M., Cohen, L.F., Pasko, A., Zehani, K., Bessais, L., Mazaleyrat, F., LoBue, M.
• Format: Article
• Language: English
• Subjects: Calorimetry; Condensed Matter; Cooling; Fe2P-based compounds; Ferromagnetism; First-order magnetic transition; Imaging; Magnetic entropy change; Magnetic fields; Magnetic materials; Magnetic refrigeration; Magnetization curves; Magnetocaloric effect; Materials Science; Physics; Spark plasma sintering; Synthesis
• ISSN: 0304-8853; 1873-4766
• DOI: 10.1016/j.jmmm.2015.08.045

Magnetocaloric materials with composition of Mn1.3Fe0.65P0.5 Si0.5 have been prepared by ball milling and solid-state reaction methods and consolidated using powder annealing, and conventional and spark plasma sintering. Magnetic and calorimetric measurements show remarkable differences upon first cooling, and slight differences on second and further coolings between the samples prepared by different synthesis routes. Further measurements using Hall probe imaging in high magnetic field have been also carried out. As-prepared samples have been cooled down just above the critical temperature, and the first phase transition has been induced by application of a magnetic field. Bulk samples show staircase isothermal magnetization curves whereas powders show smoother transition curves. •Mn–Fe–P–Si magnetocaloric materials have been prepared by different synthesis routes.•Magnetic measurements show remarkable differences upon first cooling.•First phase transition has been induced by application of a magnetic field.•Hall probe imaging in high magnetic field has also been carried out.•Bulk samples crack during the first PM–FM transition.