Hafnium and silicon carbide multilayer coatings for the protection of carbon composites

• Published in: Surface & coatings technology 2013-09, Vol.230, p.124-129
• Main Authors: Verdon, C., Szwedek, O., Jacques, S., Allemand, A., Le Petitcorps, Y.
• Format: Article
• Language: English
• Subjects: Applied sciences; Carbides; Carbon; Chemical Sciences; Chemical vapor deposition; Coatings; Cross-disciplinary physics: materials science; rheology; CVD; Deposition; Exact sciences and technology; Hafnium; HFC; Material chemistry; Materials science; Metals. Metallurgy; Multilayers; Nonmetallic coatings; Physics; Production techniques; Refractory; Silicon carbide; Surface treatment; Surface treatments; Ultra High Temperature Ceramics
• ISSN: 0257-8972; 1879-3347
• DOI: 10.1016/j.surfcoat.2013.06.022

A solution to protect the surface of a carbon/carbon composite from oxidation at high temperature is to combine refractory carbides, such as hafnium and silicon carbides (HfC and SiC). Their depositions have been studied on flat substrates and present major protection against oxidation at high temperature (several minutes at 2000°C under air). The infiltration of these carbides layers has been observed inside the open porosities of the carbon substrate which enhance the adhesion of the protection. The low pressure chemical vapor deposition (LPCVD) process developed here allows multilayer HfC/SiC depositions. The HfC coatings have various morphologies and thicknesses depending on the experimental conditions (temperature, pressure, dilution). This carbide has been firstly deposited over flat graphite substrates and carbon single fibers. Secondly, the multilayer coating deposition over a C/C composite and over carbon single fibersis studied. Finally, HfC layers have been infiltrated inside carbon fiber tows. To avoid the notch effect on the carbon fibers, a thin layer of pyrocarbon (50nm thick) has been deposited prior to the growth of the carbides. All the coatings were done in a hot wall CVD reactor and their morphologies and chemical compositions characterized by scanning electron microscopy. •HfC and HfC/SiC multilayer coatings were deposited on fibers and flat substrates.•The kinetics of the HfC CVD growth was studied as a function of temperature.•The morphology dependence of HfC with the growth temperatures is reported.•The capacity of HfC infiltration within carbon fiber tows is evaluated.