Solvent free hydrostannation and Stille reactions using ionic liquid supported organotin reagents

Hydrostannation reactions were performed cleanly using ionic liquid supported organotin reagents. These green reducing agents were used both under free radical and palladium-catalyzed conditions. One of the new ionic liquid supported organotin reagents so obtained was evaluated successfully in Still...

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Bibliographic Details
Published in:Tetrahedron 2013-07, Vol.69 (26), p.5421-5425
Main Authors: Faye, Djibril, Vybornyi, Mykhailo, Boeda, Fabien, Legoupy, Stéphanie
Format: Article
Language:English
Subjects:
Alcohols
Alkynes
Chemical reactions
Chemical Sciences
Cleaning
Free radicals
Hydrostannation
Ionic liquid
Ionic liquids
Palladium
Reducing agents
Solvents
Stille reaction
Tetrahedrons
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Summary:Hydrostannation reactions were performed cleanly using ionic liquid supported organotin reagents. These green reducing agents were used both under free radical and palladium-catalyzed conditions. One of the new ionic liquid supported organotin reagents so obtained was evaluated successfully in Stille cross-coupling reactions to give aryl-substituted allylic alcohols in solvent free conditions. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2013.04.116