The Transport and Growth of Soot Particles in Laminar Diffusion Flames

• Published in: Combustion science and technology 1987-06, Vol.53 (2-3), p.89-115
• Main Authors: Santoro, R. J., Yeh, T. T., Horvath, J. J., Semerjian, H. G.
• Format: Article
• Language: English
• Subjects: Catalysis; Catalysts: preparations and properties; Catalytic reactions; Chemistry; Exact sciences and technology; General and physical chemistry; General. Nomenclature, chemical documentation, computer chemistry; Theory of reactions, general kinetics; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
• ISSN: 0010-2202; 1563-521X
• DOI: 10.1080/00102208708947022

The Transport and Growth of Soot Particles in Laminar Diffusion Flames Abstract-The formation, growth and burnout of soot particles is examined in a series of ethene/air laminar diffusion flames. Detailed particle, temperature and velocity field measurements are utilized to investigate soot growth along individual particle paths. The importance of changes in the particle residence time, flame geometry and growth rates are evaluated as a function of fuel flow rate. Emphasis is given to the soot volume fraction measurements in two characteristic regions of the flame: the annular region near the flame front where soot is first observed to form, and the center line of the flame. In the annular region, increases in the residence time with increasing fuel flow rate are found to be the major reason for increased soot formation. The rates of soot formation are found to be similar in this region for the range of flow rates investigated. Along the center line, the soot formation processes are observed to be very similar for different flow rates if differences in the temperature-time history are taken into account by introducing a minimum temperature at which soot formation is observed. In the present work, this temperature was found to be near 1300 K. From these result s. it is concluded that processes occurring in the annular region are controlling the transition from a nonsmoking to a smoking flame. Detailed particle size and number den sity measurements obtained in these flames are also discussed.