Controlled synthesis of the antiperovskite oxide superconductor Sr3−xSnO

• Published in: Superconductor science & technology 2018-04, Vol.31 (5)
• Main Authors: Hausmann, J N, Oudah, M, Ikeda, A, Yonezawa, S, Maeno, Y
• Format: Article
• Language: English
• Subjects: antiperovskite oxide; Dirac semimetal; inverse perovskite oxide; superconductor synthesis; topological superconductor
• ISSN: 0953-2048; 1361-6668
• DOI: 10.1088/1361-6668/aab6c2

A large variety of perovskite oxide superconductors are known, including some of the most prominent high-temperature and unconventional superconductors. However, superconductivity among the oxidation state inverted material class, the antiperovskite oxides, was recently reported for the first time. In this superconductor, Sr3−xSnO, the unconventional ionic state Sn4− is realized and possible unconventional superconductivity due to a band inversion has been discussed. Here, we discuss an improved facile synthesis method, making it possible to control the strontium deficiency in Sr3−xSnO. Additionally, a synthesis method above the melting point of Sr3SnO is presented. We show temperature dependence of magnetization and electrical resistivity for superconducting strontium deficient Sr3−xSnO (Tc ∼ 5 K) and for Sr3SnO without a superconducting transition in alternating current susceptibility down to 0.15 K. Further, we reveal a significant effect of strontium raw material purity on the superconductivity and achieve substantially increased M/MMeissner (∼1) compared to the highest value reported so far. More detailed characterizations utilizing powder x-ray diffraction and energy-dispersive x-ray spectroscopy show that a minor cubic phase, previously suggested to be another Sr3−xSnO phase with a slightly larger lattice parameter, is SrO. The improved characterization and controlled synthesis reported herein enable detailed investigations on the superconducting nature and its dependency on the strontium deficiency in Sr3−xSnO.