Neutron Imaging Experiments to Study Mass Transport in Commercial Titanium Felt Porous Transport Layers

• Published in: Journal of the Electrochemical Society 2023-06, Vol.170 (6), p.64507
• Main Authors: Altaf, H., Milicic, T., Vidakovic-Koch, T., Tsotsas, E., Tengattini, Alessandro, Kardjilov, N., Arlt, T., Manke, I., Vorhauer-Huget, N.
• Format: Article
• Language: English
• ISSN: 0013-4651; 1945-7111
• DOI: 10.1149/1945-7111/acd7a8

In this work, neutron imaging was used to visualize and study invasion phenomena in fibrous porous transport layers (PTLs) of titanium felt under different flow conditions of gas and liquid phase. The experiments were realized with flow cells that contained a gas and a liquid flow channel separated by PTLs with different thicknesses and pore size distributions. The invasion can be characterized by counter-current flow of water and air with joint imbibition and drainage processes. The dynamics were visualized with neutron radiography with a local resolution of 6.5 μ m and a temporal resolution of 0.1 s. Individual static gas-liquid distributions were additionally studied by neutron tomography, with a local resolution of 22 μ m and an exposure time of 1.5 s per image (projections: 800/360°). It is shown and discussed that the invasion occurred in continuously repeated imbibition/drainage cycles with frequencies depending on the flow conditions and the PTL structure as well. The change of the PTL saturation with air or water appeared almost independent from the specific PTL structure and the breakthrough of the gas phase occurred at almost constant positions.