Visible-Light Photoactivity of Nitrogen-Doped TiO2:  Photo-oxidation of HCO2H to CO2 and H2O

• Published in: Journal of physical chemistry. C 2007-10, Vol.111 (42), p.15357-15362
• Main Authors: Balcerski, William, Ryu, Su Young, Hoffmann, Michael R
• Format: Article
• Language: English
• ISSN: 1932-7447; 1932-7455
• DOI: 10.1021/jp074989o

Nitrogen-doped TiO2 was synthesized by high-temperature exposure of TiO2 to ammonia. The catalytic efficiency was tested by monitoring the photocatalytic degradation of formate (HCO2 -) to CO2 and H2O under visible-light irradiation. The N-doped TiO2 powders were found to be active for the degradation of formic acid under visible light. However, the catalytic efficiency of the N-doped TiO2 under UV light alone is less than that of the pure TiO2 starting material. FTIR evidence indicates that the visible-light-active N-doped TiO2 has defect sites in the form of Ti−N triple bonds and that the increase of these sites leads to a loss of crystallinity that accounts for the reduced photocatalytic activity under UV irradiation. An optimal synthesis temperature of 550 °C was determined as a balance point between catalyst crystallinity and the presence of defect sites that absorb visible-light photons.