THE BINARY (ANHYDROUS) SYSTEMS NaNO3-LiNO3, LiClO3-NaClO3, LiClO3-LiNO3, NaNO3-NaClO3 AND THE QUATERNARY SYSTEM NaNO3-LiNO3-LiClO3-NaClO3

The equilibrium diagrams of the systems NaNO 3 -LiNO 3 , LiClO 3 -NaClO 3 , LiClO 3 -LiNO 3 , NaNO 3 -NaClO 3 , and NaNO 3 -LiNO 3 -LiClO 3 -NaClO 3 have been investigated by thermal analysis and, to some extent, by X-ray powder photography. All the binary systems are of the simple eutectic type, ac...

Full description

Saved in:
Bibliographic Details
Published in:Canadian journal of chemistry 1962-07, Vol.40 (7), p.1258-1265
Main Authors: Campbell, A. N, Kartzmark, E. M, Nagarajan, M. K
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The equilibrium diagrams of the systems NaNO 3 -LiNO 3 , LiClO 3 -NaClO 3 , LiClO 3 -LiNO 3 , NaNO 3 -NaClO 3 , and NaNO 3 -LiNO 3 -LiClO 3 -NaClO 3 have been investigated by thermal analysis and, to some extent, by X-ray powder photography. All the binary systems are of the simple eutectic type, accompanied, in one instance, by considerable solid solubility. The allotropic transformation of sodium nitrate complicates the equilibria involving sodium nitrate somewhat, especially when there is solid solution.The quaternary diagram shows that in the (fused) reaction lithium nitrate and sodium chlorate constitute the stable solid pair. The two invariant points of this system are both congruent.
ISSN:0008-4042
1480-3291
DOI:10.1139/v62-194