Effect of Curing Mechanism on Sulfuric Acid Corrosion Resistance of Geopolymer Recycled Aggregate Concrete

• Published in: KSCE journal of civil engineering 2024, 28(4), , pp.1173-1182
• Main Authors: Chen, Zhenmeng, Liu, Hui, Zhu, Pinghua, Li, Haichao, Ge, Tianze, Yang, Lei, Chen, Chunhong, Dong, Yanlong
• Format: Article
• Language: English
• Subjects: Accelerated tests; Acid resistance; Aggregates; Channel pores; Civil Engineering; Compressive strength; Concrete; Concrete aggregates; Corrosion; Corrosion effects; Corrosion mechanisms; Corrosion rate; Corrosion resistance; Curing; Curing (processing); Energy conservation; Engineering; Environmental Engineering; Geopolymers; Geotechnical Engineering & Applied Earth Sciences; Heat resistance; High temperature; Industrial applications; Industrial Pollution Prevention; Mechanical properties; Microcracks; Neutralization; Recycled materials; Room temperature; Sulfuric acid; Sulphuric acid; Temperature; Voids; 토목공학
• ISSN: 1226-7988; 1976-3808
• DOI: 10.1007/s12205-024-2518-x

To explore the effect of curing mechanism on the mechanical properties and sulfuric acid corrosion resistance of the geopolymer recycled aggregate concrete (GRAC), the specimens were cured at high temperature (60°C, 80°C) for 6 h, 24 h and 48 h respectively, and then lasted up to 7 d at room temperature. After the curing period was over, the laboratory accelerated simulation test of specimens was carried out by the periodic immersion method: the GRAC specimens (ϕ 50 × 100 mm) were immersed in the sulfuric acid solution with pH = 1 for 5 d and then dried at room temperature for 24 h, with a total circulation of 90 d. The results showed that after being eroded by sulfuric acid solution, the GRAC specimens cured at 60°C for 48 h had higher compressive strength with 19.9 MPa, lower mass loss rate (only 0.23%) and neutralization depth (5.71 mm) than those under other curing time. The GRAC specimens cured 80°C for 24 h also had a good performance: compressive strength achieved 16.9 MPa and had lower neutralization depth (5.99 mm), which was less affected by sulfuric acid corrosion. However, the GRAC specimens cured at 60°C for 48 h had the better mechanical properties than that cured at 80°C for 24 h. Excessive high temperature curing (80°C) would lead to more voids and microcracks inside GRAC, and destroy the dense structure, thereby reducing mechanical property of concrete. These voids and pores provided more erosion channels for sulfuric acid solution, which accelerated the corrosion rate. From the point of view of energy saving and concrete performance, no more than 60°C of curing temperature is recommended for industrial use.