The temperature dependent electrical transport in biphenyl derivatives

The d.c. electrical conductivity measurements as a function of temperature of 4,4-dibromobiphenyl (DBrBP), 4,4-dichlorobiphe-nyl (DClBP) and 4,4-dimethoxybiphenyl (DMOBP) compounds have been carried out. The eects of conformational change withinskeleton of these compounds upon optical or thermal exc...

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Bibliographic Details
Published in:Current applied physics 2006, 6(1), , pp.71-75
Main Authors: M.M. Sallam, B.A. El-Sayed, A.A. Abdel-Shafi
Format: Article
Language:Korean
Subjects:
물리학
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Summary:The d.c. electrical conductivity measurements as a function of temperature of 4,4-dibromobiphenyl (DBrBP), 4,4-dichlorobiphe-nyl (DClBP) and 4,4-dimethoxybiphenyl (DMOBP) compounds have been carried out. The eects of conformational change withinskeleton of these compounds upon optical or thermal excitation (S1 S0 para substituents on the electrical conductivityhave been discussed. The conduction processes were interpreted in the light of their molecular spectroscopic data of the infrared,ultraviolet and emission spectra as a hopping processes. The semiconducting properties of the investigated compounds were arisingfrom electron-delocalization via intramolecular interaction ofp-electrons of (C@ C) bonds and electron-donating groups inparaincreases the possibility of electron-delocalization and the interaction ofp-electron system.. KCI Citation Count: 3
ISSN:1567-1739
1878-1675