Adsorption of p-chlorophenol and p-nitrophenol in single and binary systems from solution using magnetic activated carbon

• Published in: The Korean journal of chemical engineering 2019, 36(6), 231, pp.942-953
• Main Authors: Rong, Yachan, Han, Runping
• Format: Article
• Language: English
• Subjects: Activated carbon; Adsorbents; Adsorption; Binary system; Binary systems; Biotechnology; Catalysis; Chemistry; Chemistry and Materials Science; Chlorophenol; Hydrogen bonding; Industrial Chemistry/Chemical Engineering; Materials Science; Nitrophenol; Regeneration; Sodium hydroxide; 화학공학
• ISSN: 0256-1115; 1975-7220
• DOI: 10.1007/s11814-019-0267-1

Magnetic activated carbon (MAC) was prepared by co-precipitation. These particles had attractive adsorption capacity and could be easily separated from aqueous. MAC was used as adsorbent to remove p -chlorophenol ( p -CP) and p -nitrophenol ( p -NP) from solution in single and binary systems. In a single system, the equilibrium time was 60 min, the best initial pH was 3-8 and 3-6 for p -CP or p -NP adsorption, respectively. The existence of salt ions had little influence on the adsorption process, while surfactant had negative influence. The adsorption quantity from experiments was up to 97.3 mg·g −1 for p-CP and 116 mg·g −1 for p -NP at 293 K, respectively. Freundlich model and pseudo-second-order kinetic model fitted well the adsorption behavior. Thermodynamic parameters were calculated and the results showed that the process was spontaneous, exothermic and entropy production in nature. In addition, p -CP or p -NP-loaded MAC could be well reused by 0.01 mol·L −1 sodium hydroxide solution as regeneration agent. Kinetic process of desorption was fitted best by pseudo-second-order kinetic model. Results from the binary system showed that competitive adsorption existed during the process, and p -NP adsorption on MAC was easier than p -CP. Freundlich model well fitted the adsorption behavior in the binary system. Hydrogen-bonding, electron donor-acceptor and π-π interactions may be the main mechanisms of adsorption. MAC proved to be an excellent adsorbent for the removal of p -CP and p -NP from solution.