Trimethyl-Ammonium Alkaline Anion Exchange Membranes with the Vinylbenzyl Chloride/Acrylonitrile Main Chain

• Published in: Macromolecular research 2021, 29(7), , pp.494-504
• Main Authors: Li, Zhenghan, Chen, Junjie, Zhou, JinYue, Nie, YiWen, Shen, Chunhui, Gao, Shanjun
• Format: Article
• Language: English
• Subjects: Anion exchanging; Atomic force microscopy; Characterization and Evaluation of Materials; Chemistry; Chemistry and Materials Science; Chlorides; Complex Fluids and Microfluidics; Copolymerization; Fourier transforms; Fuel cells; Ion currents; Ion exchange; Ions; Liquid chromatography; Mechanical properties; Membranes; Nanochemistry; Nanotechnology; NMR; Nuclear fuels; Nuclear magnetic resonance; Physical Chemistry; Polymer Sciences; Polyolefins; Soft and Granular Matter; Thermal stability; Trimethylamine; 고분자공학
• ISSN: 1598-5032; 2092-7673
• DOI: 10.1007/s13233-021-9054-z

The main chain of polyolefin was synthesized by copolymerization of 4 — vinylbenzyl chloride (VBC) and acrylonitrile (AN), and trimethylamine is used for quaternization to prepare heterogeneous benzyl trimethyl-ammonium anion exchange membranes (Heter-X) and homogeneous benzyl trimethyl-ammonium anion exchange membrane (Homo-X). The results of Fourier-transform infrared (FT-IR), gel permeation chromatography (GPC), and 1 H nuclear magnetic resonance (NMR) showed that VBC and AN were successfully copolymerized to form a polymer with a certain molecular weight, and trimethylamine was successfully quaternized. The prepared membranes exhibited good thermal stability and mechanical properties. The theoretical ion exchange capacity (IEC) values of Homo-3 and Heter-3 are the same, but the conductivity at 80 °C were 0.0572 S cm −1 and 0.0505 S cm −1 . The results showed that the homogeneous method has a higher degree of quaternization and a more uniform distribution of quaternary ammonium groups, forming a more obvious microphase separation structure, which can also be seen in the atomic force microscopy (AFM) diagram. After being soaked in 1 M KOH solution for 480 h, the ionic conductivity of Homo-6 and Heter-6 can still remain 91.4% and 85.5%, and the IEC loss rates were 17.21% and 24.34%. These results indicate that the prepared membranes are promising materials for application in fuel cells.