Water vapor oxidation of SiC layer in surrogate TRISO fuel particles

• Published in: Composites. Part B, Engineering Engineering, 2021-06, Vol.215 (C), p.108807, Article 108807
• Main Authors: Cho, Yi Je, Lu, Kathy
• Format: Article
• Language: English
• Subjects: Accidental condition; Oxidation; SiC layer; TRISO fuel particle; Water vapor
• ISSN: 1359-8368; 1879-1069
• DOI: 10.1016/j.compositesb.2021.108807

Under accidental conditions for high temperature gas-cooled reactors (HTGR), the SiC layer in tri-structural-isotropic (TRISO) fuel particles can be exposed to water vapor. In this study, oxidation behaviors of surrogate TRISO fuel particles were investigated in a He-20 vol% water vapor mixed atmosphere at temperatures up to 1600 °C. The growth of the crystalline oxide passivation layer with cracks and pores followed a parabolic law with time, where the maximum was 2.3 μm at 1600 °C. The oxide layer and the SiC surface under the oxide became flattened with increasing temperature, as a function of the silica viscosity and the diffusion path of water vapor. Volatilization of the oxide layer was analyzed using a mechanistic model that an inert gas in oxidizing atmospheres could influence the magnitude of volatilization. The fracture load and strength of the oxidized and thinned SiC layer were numerically estimated to decrease from 2.27 to 1.69 N and from 317 to 299 MPa, respectively, with the SiC thickness decrease from 35 to 32 μm. This prediction indicates that the oxidized SiC layer should retain fission products. Additionally, the mechanical integrity of each layer in the TRISO fuel particle after oxidation was evaluated. The results in this work provide important data for the safety analysis of accidental scenarios in HTGRs. [Display omitted]