Linear and nonlinear viscoelasticity of concentrated thermoresponsive microgel suspensions

We present an integrated experimental and theoretical study of the dynamics and rheology of self-crosslinked, slightly charged, temperature responsive soft poly(N-isopropylacrylamide) (pNIPAM) microgels over a wide range of concentration and temperature spanning the sharp change in particle size and...

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Bibliographic Details
Published in:Journal of colloid and interface science 2021-05, Vol.601
Main Authors: Chaudhary, Gaurav, Ghosh, Ashesh, Kang, Jin Gu, Braun, Paul V., Ewoldt, Randy H., Schweizer, Kenneth S.
Format: Article
Language:English
Subjects:
Attractive microgels
Colloidal rheology
Concentrated suspension
ENGINEERING
pNIPAM microgels
Statistical mechanical theory
Thermoresponsive colloids
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Summary:We present an integrated experimental and theoretical study of the dynamics and rheology of self-crosslinked, slightly charged, temperature responsive soft poly(N-isopropylacrylamide) (pNIPAM) microgels over a wide range of concentration and temperature spanning the sharp change in particle size and intermolecular interactions across the lower critical solution temperature (LCST). Dramatic, non-monotonic changes in viscoelasticity are observed as a function of temperature, with distinct concentration dependence in the dense fluid, glassy, and soft-jammed regimes. Motivated by our experimental observations, we formulate a minimalistic model for the size dependence of a single microgel particle and the change of the interparticle interaction from purely repulsive to attractive upon heating. Using microscopic equilibrium and time-dependent statistical mechanical theories, theoretical predictions are quantitatively compared with experimental measurements of the shear modulus. Good agreement is found for the nonmonotonic temperature behavior that originates as a consequence of the competition between reduced microgel packing fraction and increasing interparticle attractions. Furthermore, testable predictions are made for nonlinear rheological properties such as the yield stress and strain. To our knowledge, this is the first attempt to quantitatively understand in a unified manner the viscoelasticity of dense, temperature-responsive microgel suspensions spanning a wide range of temperatures and concentrations.
ISSN:0021-9797
1095-7103