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Rhenium ohmic contacts on 6H-SiC
Rhenium (Re) thin-film contacts (100-nm thick) were deposited on carbon-rich, nominally stoichiometric, and silicon-rich 6H–SiC surfaces, which were moderately doped with nitrogen (1.28×1018cm−3). Morphology (Dektak), phase formation (x-ray diffraction), chemistry (Auger electron spectroscopy), and...
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Published in: | Journal of applied physics 2004-11, Vol.96 (9), p.5357-5364 |
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container_end_page | 5364 |
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container_title | Journal of applied physics |
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creator | McDaniel, G. Y. Fenstermaker, S. T. Lampert, W. V. Holloway, P. H. |
description | Rhenium (Re) thin-film contacts (100-nm thick) were deposited on carbon-rich, nominally stoichiometric, and silicon-rich 6H–SiC surfaces, which were moderately doped with nitrogen (1.28×1018cm−3). Morphology (Dektak), phase formation (x-ray diffraction), chemistry (Auger electron spectroscopy), and electrical properties (I–V) were characterized for the as-deposited and annealed (120min, 1000°C, vacuum |
doi_str_mv | 10.1063/1.1797550 |
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Y. ; Fenstermaker, S. T. ; Lampert, W. V. ; Holloway, P. H.</creator><creatorcontrib>McDaniel, G. Y. ; Fenstermaker, S. T. ; Lampert, W. V. ; Holloway, P. H.</creatorcontrib><description>Rhenium (Re) thin-film contacts (100-nm thick) were deposited on carbon-rich, nominally stoichiometric, and silicon-rich 6H–SiC surfaces, which were moderately doped with nitrogen (1.28×1018cm−3). Morphology (Dektak), phase formation (x-ray diffraction), chemistry (Auger electron spectroscopy), and electrical properties (I–V) were characterized for the as-deposited and annealed (120min, 1000°C, vacuum <1×10−6Torr) contacts. As-deposited films were nonohmic. Films grown on carbon-rich surfaces were nonspecular, granular, and often delaminated during characterization. At room temperature in air, the Re films on stoichiometric SiC remained optically specular reflecting for 3h, but then became hazy from oxidation. The Re films on silicon-rich surfaces, stored in air at room temperature, resisted ex situ oxidation for approximately 24h. The annealed samples remained specular without visible signs of oxidation. The annealing resulted in a reduction in surface roughness for all the films regardless of substrate chemistry. The phase separation between carbon and rhenium was observed based on the formation of interfacial Re clusters and a ∼10-nm graphite surface layer after annealing. Auger data showed that Si layers (5–10nm) deposited to create Si-rich surfaces were partially consumed to form rhenium silicide during annealing, and the sharp Re∕Si∕SiC interface became more diffused with Re detected ∼50nm deeper into the structure. The annealing of Re films on moderately doped (1.28×1018cm−3) SiC resulted in ohmic contacts with an average specific contact resistance of 7.0×10−5Ωcm2 for stoichiometric and 1.6×10−5Ωcm2 for silicon-rich samples. 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Y.</creatorcontrib><creatorcontrib>Fenstermaker, S. T.</creatorcontrib><creatorcontrib>Lampert, W. V.</creatorcontrib><creatorcontrib>Holloway, P. H.</creatorcontrib><title>Rhenium ohmic contacts on 6H-SiC</title><title>Journal of applied physics</title><description>Rhenium (Re) thin-film contacts (100-nm thick) were deposited on carbon-rich, nominally stoichiometric, and silicon-rich 6H–SiC surfaces, which were moderately doped with nitrogen (1.28×1018cm−3). Morphology (Dektak), phase formation (x-ray diffraction), chemistry (Auger electron spectroscopy), and electrical properties (I–V) were characterized for the as-deposited and annealed (120min, 1000°C, vacuum <1×10−6Torr) contacts. As-deposited films were nonohmic. Films grown on carbon-rich surfaces were nonspecular, granular, and often delaminated during characterization. At room temperature in air, the Re films on stoichiometric SiC remained optically specular reflecting for 3h, but then became hazy from oxidation. The Re films on silicon-rich surfaces, stored in air at room temperature, resisted ex situ oxidation for approximately 24h. The annealed samples remained specular without visible signs of oxidation. The annealing resulted in a reduction in surface roughness for all the films regardless of substrate chemistry. The phase separation between carbon and rhenium was observed based on the formation of interfacial Re clusters and a ∼10-nm graphite surface layer after annealing. Auger data showed that Si layers (5–10nm) deposited to create Si-rich surfaces were partially consumed to form rhenium silicide during annealing, and the sharp Re∕Si∕SiC interface became more diffused with Re detected ∼50nm deeper into the structure. The annealing of Re films on moderately doped (1.28×1018cm−3) SiC resulted in ohmic contacts with an average specific contact resistance of 7.0×10−5Ωcm2 for stoichiometric and 1.6×10−5Ωcm2 for silicon-rich samples. The annealed contacts on carbon-rich surfaces remained rectifying.</description><subject>ANNEALING</subject><subject>AUGER ELECTRON SPECTROSCOPY</subject><subject>DEPOSITION</subject><subject>DOPED MATERIALS</subject><subject>ELECTRICAL PROPERTIES</subject><subject>ELECTRON BEAMS</subject><subject>GRAPHITE</subject><subject>INTERFACES</subject><subject>MATERIALS SCIENCE</subject><subject>MORPHOLOGY</subject><subject>NITROGEN</subject><subject>OXIDATION</subject><subject>RHENIUM</subject><subject>ROUGHNESS</subject><subject>SEMICONDUCTOR MATERIALS</subject><subject>SILICON CARBIDES</subject><subject>STOICHIOMETRY</subject><subject>SUBSTRATES</subject><subject>TEMPERATURE RANGE 0273-0400 K</subject><subject>THIN FILMS</subject><subject>X-RAY DIFFRACTION</subject><issn>0021-8979</issn><issn>1089-7550</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNotkE1LAzEYhIMouFYP_oMFTx5S3zdpvo6yaCsUBD_OIc0HG3F3ZRMP_ntb2tPM4WFmGEJuEZYIkj_gEpVRQsAZaRC0oQd_ThoAhlQbZS7JVSlfAIiam4a0b30c8-_QTv2QfeunsTpfSzuNrdzQ99xdk4vkvku8OemCfD4_fXQbun1dv3SPW-qZEJUaDBj8oRt2STkhAxipd5KJkBA5h5XzamU4ItOaY0RQzEV0GEISkDhfkLtj7lRqtsXnGn2_nzNGXy0DKRlK2FP3R8rPUylzTPZnzoOb_yyCPRxg0Z4O4P_og0kp</recordid><startdate>20041101</startdate><enddate>20041101</enddate><creator>McDaniel, G. 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H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c255t-91d1dc17970bf7a56d0968b625df113304ac74931128831e1072ae1a1ddf50f33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>ANNEALING</topic><topic>AUGER ELECTRON SPECTROSCOPY</topic><topic>DEPOSITION</topic><topic>DOPED MATERIALS</topic><topic>ELECTRICAL PROPERTIES</topic><topic>ELECTRON BEAMS</topic><topic>GRAPHITE</topic><topic>INTERFACES</topic><topic>MATERIALS SCIENCE</topic><topic>MORPHOLOGY</topic><topic>NITROGEN</topic><topic>OXIDATION</topic><topic>RHENIUM</topic><topic>ROUGHNESS</topic><topic>SEMICONDUCTOR MATERIALS</topic><topic>SILICON CARBIDES</topic><topic>STOICHIOMETRY</topic><topic>SUBSTRATES</topic><topic>TEMPERATURE RANGE 0273-0400 K</topic><topic>THIN FILMS</topic><topic>X-RAY DIFFRACTION</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>McDaniel, G. Y.</creatorcontrib><creatorcontrib>Fenstermaker, S. T.</creatorcontrib><creatorcontrib>Lampert, W. V.</creatorcontrib><creatorcontrib>Holloway, P. H.</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Journal of applied physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>McDaniel, G. Y.</au><au>Fenstermaker, S. T.</au><au>Lampert, W. V.</au><au>Holloway, P. H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rhenium ohmic contacts on 6H-SiC</atitle><jtitle>Journal of applied physics</jtitle><date>2004-11-01</date><risdate>2004</risdate><volume>96</volume><issue>9</issue><spage>5357</spage><epage>5364</epage><pages>5357-5364</pages><issn>0021-8979</issn><eissn>1089-7550</eissn><abstract>Rhenium (Re) thin-film contacts (100-nm thick) were deposited on carbon-rich, nominally stoichiometric, and silicon-rich 6H–SiC surfaces, which were moderately doped with nitrogen (1.28×1018cm−3). Morphology (Dektak), phase formation (x-ray diffraction), chemistry (Auger electron spectroscopy), and electrical properties (I–V) were characterized for the as-deposited and annealed (120min, 1000°C, vacuum <1×10−6Torr) contacts. As-deposited films were nonohmic. Films grown on carbon-rich surfaces were nonspecular, granular, and often delaminated during characterization. At room temperature in air, the Re films on stoichiometric SiC remained optically specular reflecting for 3h, but then became hazy from oxidation. The Re films on silicon-rich surfaces, stored in air at room temperature, resisted ex situ oxidation for approximately 24h. The annealed samples remained specular without visible signs of oxidation. The annealing resulted in a reduction in surface roughness for all the films regardless of substrate chemistry. The phase separation between carbon and rhenium was observed based on the formation of interfacial Re clusters and a ∼10-nm graphite surface layer after annealing. Auger data showed that Si layers (5–10nm) deposited to create Si-rich surfaces were partially consumed to form rhenium silicide during annealing, and the sharp Re∕Si∕SiC interface became more diffused with Re detected ∼50nm deeper into the structure. The annealing of Re films on moderately doped (1.28×1018cm−3) SiC resulted in ohmic contacts with an average specific contact resistance of 7.0×10−5Ωcm2 for stoichiometric and 1.6×10−5Ωcm2 for silicon-rich samples. The annealed contacts on carbon-rich surfaces remained rectifying.</abstract><cop>United States</cop><doi>10.1063/1.1797550</doi><tpages>8</tpages></addata></record> |
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subjects | ANNEALING AUGER ELECTRON SPECTROSCOPY DEPOSITION DOPED MATERIALS ELECTRICAL PROPERTIES ELECTRON BEAMS GRAPHITE INTERFACES MATERIALS SCIENCE MORPHOLOGY NITROGEN OXIDATION RHENIUM ROUGHNESS SEMICONDUCTOR MATERIALS SILICON CARBIDES STOICHIOMETRY SUBSTRATES TEMPERATURE RANGE 0273-0400 K THIN FILMS X-RAY DIFFRACTION |
title | Rhenium ohmic contacts on 6H-SiC |
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