Nanocone‐Modified Surface Facilitates Gas Bubble Detachment for High‐Rate Alkaline Water Splitting

• Published in: Advanced energy materials 2023-10, Vol.13 (39)
• Main Authors: Ren, Qiu, Feng, Longsheng, Ye, Congwang, Xue, Xinzhe, Lin, Dun, Eisenberg, Samuel, Kou, Tianyi, Duoss, Eric B., Zhu, Cheng, Li, Yat
• Format: Article
• Language: English
• Subjects: Bubbles; Diffusion barriers; Electrodes; Metal foams; Metal foils; Nickel; Surface layers; Three dimensional printing; Water splitting
• ISSN: 1614-6832; 1614-6840
• DOI: 10.1002/aenm.202302073

The significant amount of gas bubbles generated during high‐rate alkaline water splitting (AWS) can be detrimental to the process. The accumulation of bubbles will block the active catalytic sites and hinder the ion and electrolyte diffusion, limiting the maximum current density. Furthermore, the detachment of large bubbles can also damage the electrode's surface layer. Here, a general strategy for facilitating bubble detachment is demonstrated by modifying the nickel electrode surface with nickel nanocone nanostructures, which turns the surface into underwater superaerophobic. Simulation and experimental data show that bubbles take a considerably shorter time to detach from the nanocone‐modified nickel foil than the unmodified foil. As a result, these bubbles also have a smaller detachment size and less chance for bubble coalescence. The nanocone‐modified electrodes, including nickel foil, nickel foam, and 3D‐printed nickel lattice, all show substantially reduced overpotentials at 1000 mA cm −2 compared to their pristine counterpart. The electrolyzer assembled with two nanocone‐modified nickel lattice electrodes retains >95% of the performance after testing at ≈900 mA cm −2 for 100 h. The surface NC structure is also well preserved. The findings offer an exciting and simple strategy for enhancing the bubble detachment and, thus, the electrode activity for high‐rate AWS.