Elucidating the degradation mechanisms of Pt-free anode anion-exchange membrane fuel cells after durability testing

• Published in: Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2024-04, Vol.12 (17), p.1435-1448
• Main Authors: Douglin, John C, Singh, Ramesh K, Yang-Neyerlin, Ami C, He, Cheng, Yassin, Karam, Miller, Hamish A, Pagliaro, Maria V, Capozzoli, Laura, Carbo-Argibay, Enrique, Brandon, Simon, Ferreira, Paulo J, Pivovar, Bryan S, Dekel, Dario R
• Format: Article
• Language: English
• Subjects: 08 HYDROGEN; 30 DIRECT ENERGY CONVERSION; Anion exchanging; anion-exchange membrane fuel cells; Anions; Anodes; Carbon dioxide; Catalysts; cell durability; Cerium oxides; Current density; Degradation; Durability; Electrocatalysts; Fuel cells; Fuel technology; Ionomers; Membranes; Mitigation; mitigation strategies; Palladium; Platinum; Stability; Stability analysis; Toughness
• ISSN: 2050-7488; 2050-7496
• DOI: 10.1039/d3ta07065d

The development of anion-exchange membrane fuel cells (AEMFCs) has recently accelerated due to synergistic improvements yielding highly conductive membranes, stable ionomers, and enhanced alkaline electrocatalysts. However, cell durability, especially under realistic conditions, still poses a major challenge. Herein, we employ low-loadings of Pt-free Pd-based catalysts in the anode of AEMFCs and elucidate potential degradation mechanisms impacting long-term performance under conditions analogous to the real-world (high current density, H 2 -air (albeit CO 2 -free), and intermittent operation). Our high-performing AEMFCs achieve impressive performance with power densities approaching 1 W cm −2 and current densities up to 3.5 A cm −2 . Over a 200 h period of continuous operation in H 2 -air at a current density of 600 mA cm −2 , our model Pd/C-CeO 2 anode cell exhibits record stability (∼30 μV h −1 degradation) compared to the literature and up to 6× better stability than our Pd/C and commercial Pt/C anode cells. Following an 8 h shutdown, the Pd/C-CeO 2 anode cell was restarted and continued for an additional 300 h with a higher degradation rate of ∼600 μV h −1 . Thorough in situ evaluations and post-stability analyses provide insights into potential degradation mechanisms to be expected during extended operation under more realistic conditions and provide mitigation strategies to enable the widespread development of highly durable AEMFCs. Cell deterioration over time is one of the most perplexing obstacles to long-term fuel cell performance. In this study, we employed both in situ and ex situ analytical approaches to investigate the deterioration mechanisms of state-of-the-art AEMFCs.