Electrochemical grand potential-based phase-field simulation of electric field-assisted sintering

• Published in: Acta materialia 2024-08, Vol.275, p.120049, Article 120049
• Main Authors: Aagesen, Larry K., Pitts, Stephanie A., Harris, Brennan K., Yao, Tiankai, Robinson, Lucas D., García, R. Edwin
• Format: Article
• Language: English
• Subjects: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; EFAS; Electric field; MATERIALS SCIENCE; MATHEMATICS AND COMPUTING; Phase-field; Sintering; SPS
• ISSN: 1359-6454; 1873-2453
• DOI: 10.1016/j.actamat.2024.120049

An electrochemical grand potential functional was proposed to describe the sintering of an ionic ceramic green body. The resultant phase-field description enables simulation of the consolidation of an arbitrary number of granular particles and their interactions with the surrounding void phase. The model includes the effects of charged vacancies and the associated interactions between internal and applied electric fields. Defect segregation to grain boundaries is also accounted for, as well as enhanced interfacial defect mobilities. The model was parameterized for Y2O3. Simulations of two-particle systems showed that the applied electric field had an increasingly important impact on neck growth as particle size increased. A sudden rapid increase in temperature occurred for larger field strengths, which has been reported to be correlated to the onset of a flash event in flash sintering. Simulations of many particles showed that internal heat generation by Joule heating was localized at particle–particle contacts (grain boundaries), even though their conductivities were lower than nearby internal particle-void interfaces. A percolative path for ionic charge across the green body and the ceramic sintered solid was thus defined, accelerating the Joule heating process as the porosity of the green body is removed. [Display omitted]