The matrix pencil as a tunable filter

• Published in: Journal of magnetic resonance (1997) 2024-11, Vol.368 (C), p.107780, Article 107780
• Main Authors: Fricke, S.N., Balcom, B.J., Kaseman, D.C., Augustine, M.P.
• Format: Article
• Language: English
• Subjects: Fourier filter; Matrix pencil; NMR; Noise filter; Signal analysis
• ISSN: 1090-7807; 1096-0856; 1096-0856
• DOI: 10.1016/j.jmr.2024.107780

[Display omitted] •The MPM can be used as a filter to analytically improve NMR sensitivity.•MPF is not susceptible to aliasing and resolution reduction like Fourier filters.•Useful for pure phase correction and filtration in a single step. Despite inherent sensitivity constraints, nuclear magnetic resonance (NMR) plays an indispensable role in probing molecular structures and dynamics across scientific disciplines. Remarkably, while extensive efforts have targeted instrumental and experimental sensitivity improvements, comparatively little focus has been dedicated to sensitivity enhancement through signal analysis. Amidst this present gap, the matrix pencil method (MPM) has emerged as a versatile algorithm that offers tunable filtering and phasing capabilities. Extensive prior research has established the MPM as an adept fitting tool in signal analysis. Here, the efficacy of the MPM is investigated by precisely modeling noisy data to separate information-bearing signals from noise, thereby expanding its utility in various magnetic resonance applications. Simulated data is used to confirm the ability of the MPM to discern and separate signals from noise. Comparative analyses against standard Fourier-based filtering methods highlight the superior performance of the matrix pencil filter (MPF) in preserving signal fidelity without introducing aliasing artifacts. A variety of experimental data is then explored to demonstrate the proficiency of the MPF in characterizing signal components and correcting phase distortions. Collectively, these case studies underscore the filtering capacity of the MPM, portending its use for analytical sensitivity improvements in a wide range of NMR applications.