Loading…
Combustion synthesis of fullerenes
We report the isolation of C 60 and C 70 from combustion soot that is produced in high-temperature, low-pressure premixed flat flames. A critical parameter for high fullerene yields in combustion appears to be a very high flame temperature. Equilibrium calculations indicate that low pressures are im...
Saved in:
| Published in: | Combustion and flame 1992, Vol.88 (1), p.102-112 |
|---|---|
| Main Authors: | , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c391t-164eae9efd2edb8d837e5be69a194a9efcaa7f9b465d6cf4d2ee2fb19a28f25a3 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c391t-164eae9efd2edb8d837e5be69a194a9efcaa7f9b465d6cf4d2ee2fb19a28f25a3 |
| container_end_page | 112 |
| container_issue | 1 |
| container_start_page | 102 |
| container_title | Combustion and flame |
| container_volume | 88 |
| creator | Mckinnon, J.Thomas Bell, William L. Barkley, Robert M. |
| description | We report the isolation of C
60 and C
70 from combustion soot that is produced in high-temperature, low-pressure premixed flat flames. A critical parameter for high fullerene yields in combustion appears to be a very high flame temperature. Equilibrium calculations indicate that low pressures are important, but the experimental evidence is not clear at this time. Combustion synthesis yields fullerenes with a C
70/C
60 ratio of about 40%, as compared with the 12% reported for electric-arc-generated fullerenes. The overall yields from carbon are very low (ca. 0.03%) but the soot studied had been produced in flames that were in no way optimized for fullerene production. |
| doi_str_mv | 10.1016/0010-2180(92)90010-M |
| format | article |
| fullrecord | <record><control><sourceid>proquest_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_5697799</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>001021809290010M</els_id><sourcerecordid>25568254</sourcerecordid><originalsourceid>FETCH-LOGICAL-c391t-164eae9efd2edb8d837e5be69a194a9efcaa7f9b465d6cf4d2ee2fb19a28f25a3</originalsourceid><addsrcrecordid>eNp9kE1LAzEQhoMoWKv_wEMpInpYTbKb3eQiSPELWrzoOWSzExrZJjXZFfrvzXalR09hwjMz7zwIXRJ8RzAp7zEmOKOE4xtBb8W-Wh2hCWGszKig5BhNDsgpOovxC2NcFXk-QfOF39R97Kx3s7hz3RqijTNvZqZvWwjgIJ6jE6PaCBd_7xR9Pj99LF6z5fvL2-JxmelckC4jZQEKBJiGQlPzhucVsBpKoYgoVPrXSlVG1EXJmlKbImFATU2EotxQpvIpmo9zfYojo7Yd6LX2zoHuJCtFVQmRoOsR2gb_3UPs5MZGDW2rHPg-Sppu5pQVCSxGUAcfYwAjt8FuVNhJguVgTQ5K5KBECir31uQqtV39zVdRq9YE5bSNh16GOec0T9jDiEES8mMhDHnBaWhsGOI23v6_5xffJIA8</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>25568254</pqid></control><display><type>article</type><title>Combustion synthesis of fullerenes</title><source>Backfile Package - Energy and Power [YER]</source><creator>Mckinnon, J.Thomas ; Bell, William L. ; Barkley, Robert M.</creator><creatorcontrib>Mckinnon, J.Thomas ; Bell, William L. ; Barkley, Robert M.</creatorcontrib><description>We report the isolation of C
60 and C
70 from combustion soot that is produced in high-temperature, low-pressure premixed flat flames. A critical parameter for high fullerene yields in combustion appears to be a very high flame temperature. Equilibrium calculations indicate that low pressures are important, but the experimental evidence is not clear at this time. Combustion synthesis yields fullerenes with a C
70/C
60 ratio of about 40%, as compared with the 12% reported for electric-arc-generated fullerenes. The overall yields from carbon are very low (ca. 0.03%) but the soot studied had been produced in flames that were in no way optimized for fullerene production.</description><identifier>ISSN: 0010-2180</identifier><identifier>EISSN: 1556-2921</identifier><identifier>DOI: 10.1016/0010-2180(92)90010-M</identifier><identifier>CODEN: CBFMAO</identifier><language>eng</language><publisher>New York, NY: Elsevier Inc</publisher><subject>400800 - Combustion, Pyrolysis, & High-Temperature Chemistry ; Applied sciences ; CARBON ; CHEMICAL REACTIONS ; COMBUSTION ; Combustion. Flame ; CURRENTS ; ELECTRIC ARCS ; ELECTRIC CURRENTS ; ELECTRIC DISCHARGES ; ELEMENTS ; Energy ; Energy. Thermal use of fuels ; EQUILIBRIUM ; Exact sciences and technology ; FLAMES ; FULLERENES ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; Miscellaneous ; MIXING ; NONMETALS ; OPTIMIZATION ; OXIDATION ; PRODUCTION ; SOOT ; SYNTHESIS ; Theoretical studies. Data and constants. Metering ; THERMOCHEMICAL PROCESSES ; YIELDS</subject><ispartof>Combustion and flame, 1992, Vol.88 (1), p.102-112</ispartof><rights>1992</rights><rights>1992 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c391t-164eae9efd2edb8d837e5be69a194a9efcaa7f9b465d6cf4d2ee2fb19a28f25a3</citedby><cites>FETCH-LOGICAL-c391t-164eae9efd2edb8d837e5be69a194a9efcaa7f9b465d6cf4d2ee2fb19a28f25a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/001021809290010M$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3463,4024,27923,27924,27925,45968</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=5088823$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/5697799$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Mckinnon, J.Thomas</creatorcontrib><creatorcontrib>Bell, William L.</creatorcontrib><creatorcontrib>Barkley, Robert M.</creatorcontrib><title>Combustion synthesis of fullerenes</title><title>Combustion and flame</title><description>We report the isolation of C
60 and C
70 from combustion soot that is produced in high-temperature, low-pressure premixed flat flames. A critical parameter for high fullerene yields in combustion appears to be a very high flame temperature. Equilibrium calculations indicate that low pressures are important, but the experimental evidence is not clear at this time. Combustion synthesis yields fullerenes with a C
70/C
60 ratio of about 40%, as compared with the 12% reported for electric-arc-generated fullerenes. The overall yields from carbon are very low (ca. 0.03%) but the soot studied had been produced in flames that were in no way optimized for fullerene production.</description><subject>400800 - Combustion, Pyrolysis, & High-Temperature Chemistry</subject><subject>Applied sciences</subject><subject>CARBON</subject><subject>CHEMICAL REACTIONS</subject><subject>COMBUSTION</subject><subject>Combustion. Flame</subject><subject>CURRENTS</subject><subject>ELECTRIC ARCS</subject><subject>ELECTRIC CURRENTS</subject><subject>ELECTRIC DISCHARGES</subject><subject>ELEMENTS</subject><subject>Energy</subject><subject>Energy. Thermal use of fuels</subject><subject>EQUILIBRIUM</subject><subject>Exact sciences and technology</subject><subject>FLAMES</subject><subject>FULLERENES</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>Miscellaneous</subject><subject>MIXING</subject><subject>NONMETALS</subject><subject>OPTIMIZATION</subject><subject>OXIDATION</subject><subject>PRODUCTION</subject><subject>SOOT</subject><subject>SYNTHESIS</subject><subject>Theoretical studies. Data and constants. Metering</subject><subject>THERMOCHEMICAL PROCESSES</subject><subject>YIELDS</subject><issn>0010-2180</issn><issn>1556-2921</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1992</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWKv_wEMpInpYTbKb3eQiSPELWrzoOWSzExrZJjXZFfrvzXalR09hwjMz7zwIXRJ8RzAp7zEmOKOE4xtBb8W-Wh2hCWGszKig5BhNDsgpOovxC2NcFXk-QfOF39R97Kx3s7hz3RqijTNvZqZvWwjgIJ6jE6PaCBd_7xR9Pj99LF6z5fvL2-JxmelckC4jZQEKBJiGQlPzhucVsBpKoYgoVPrXSlVG1EXJmlKbImFATU2EotxQpvIpmo9zfYojo7Yd6LX2zoHuJCtFVQmRoOsR2gb_3UPs5MZGDW2rHPg-Sppu5pQVCSxGUAcfYwAjt8FuVNhJguVgTQ5K5KBECir31uQqtV39zVdRq9YE5bSNh16GOec0T9jDiEES8mMhDHnBaWhsGOI23v6_5xffJIA8</recordid><startdate>1992</startdate><enddate>1992</enddate><creator>Mckinnon, J.Thomas</creator><creator>Bell, William L.</creator><creator>Barkley, Robert M.</creator><general>Elsevier Inc</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><scope>OTOTI</scope></search><sort><creationdate>1992</creationdate><title>Combustion synthesis of fullerenes</title><author>Mckinnon, J.Thomas ; Bell, William L. ; Barkley, Robert M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c391t-164eae9efd2edb8d837e5be69a194a9efcaa7f9b465d6cf4d2ee2fb19a28f25a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1992</creationdate><topic>400800 - Combustion, Pyrolysis, & High-Temperature Chemistry</topic><topic>Applied sciences</topic><topic>CARBON</topic><topic>CHEMICAL REACTIONS</topic><topic>COMBUSTION</topic><topic>Combustion. Flame</topic><topic>CURRENTS</topic><topic>ELECTRIC ARCS</topic><topic>ELECTRIC CURRENTS</topic><topic>ELECTRIC DISCHARGES</topic><topic>ELEMENTS</topic><topic>Energy</topic><topic>Energy. Thermal use of fuels</topic><topic>EQUILIBRIUM</topic><topic>Exact sciences and technology</topic><topic>FLAMES</topic><topic>FULLERENES</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>Miscellaneous</topic><topic>MIXING</topic><topic>NONMETALS</topic><topic>OPTIMIZATION</topic><topic>OXIDATION</topic><topic>PRODUCTION</topic><topic>SOOT</topic><topic>SYNTHESIS</topic><topic>Theoretical studies. Data and constants. Metering</topic><topic>THERMOCHEMICAL PROCESSES</topic><topic>YIELDS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mckinnon, J.Thomas</creatorcontrib><creatorcontrib>Bell, William L.</creatorcontrib><creatorcontrib>Barkley, Robert M.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>OSTI.GOV</collection><jtitle>Combustion and flame</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mckinnon, J.Thomas</au><au>Bell, William L.</au><au>Barkley, Robert M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Combustion synthesis of fullerenes</atitle><jtitle>Combustion and flame</jtitle><date>1992</date><risdate>1992</risdate><volume>88</volume><issue>1</issue><spage>102</spage><epage>112</epage><pages>102-112</pages><issn>0010-2180</issn><eissn>1556-2921</eissn><coden>CBFMAO</coden><abstract>We report the isolation of C
60 and C
70 from combustion soot that is produced in high-temperature, low-pressure premixed flat flames. A critical parameter for high fullerene yields in combustion appears to be a very high flame temperature. Equilibrium calculations indicate that low pressures are important, but the experimental evidence is not clear at this time. Combustion synthesis yields fullerenes with a C
70/C
60 ratio of about 40%, as compared with the 12% reported for electric-arc-generated fullerenes. The overall yields from carbon are very low (ca. 0.03%) but the soot studied had been produced in flames that were in no way optimized for fullerene production.</abstract><cop>New York, NY</cop><pub>Elsevier Inc</pub><doi>10.1016/0010-2180(92)90010-M</doi><tpages>11</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0010-2180 |
| ispartof | Combustion and flame, 1992, Vol.88 (1), p.102-112 |
| issn | 0010-2180 1556-2921 |
| language | eng |
| recordid | cdi_osti_scitechconnect_5697799 |
| source | Backfile Package - Energy and Power [YER] |
| subjects | 400800 - Combustion, Pyrolysis, & High-Temperature Chemistry Applied sciences CARBON CHEMICAL REACTIONS COMBUSTION Combustion. Flame CURRENTS ELECTRIC ARCS ELECTRIC CURRENTS ELECTRIC DISCHARGES ELEMENTS Energy Energy. Thermal use of fuels EQUILIBRIUM Exact sciences and technology FLAMES FULLERENES INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Miscellaneous MIXING NONMETALS OPTIMIZATION OXIDATION PRODUCTION SOOT SYNTHESIS Theoretical studies. Data and constants. Metering THERMOCHEMICAL PROCESSES YIELDS |
| title | Combustion synthesis of fullerenes |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-26T04%3A02%3A57IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Combustion%20synthesis%20of%20fullerenes&rft.jtitle=Combustion%20and%20flame&rft.au=Mckinnon,%20J.Thomas&rft.date=1992&rft.volume=88&rft.issue=1&rft.spage=102&rft.epage=112&rft.pages=102-112&rft.issn=0010-2180&rft.eissn=1556-2921&rft.coden=CBFMAO&rft_id=info:doi/10.1016/0010-2180(92)90010-M&rft_dat=%3Cproquest_osti_%3E25568254%3C/proquest_osti_%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c391t-164eae9efd2edb8d837e5be69a194a9efcaa7f9b465d6cf4d2ee2fb19a28f25a3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=25568254&rft_id=info:pmid/&rfr_iscdi=true |