Lithium intercalation into SnS[sub 2](CoCp[sub 2])[sub x]

The search for suitable lightweight rechargeable batteries has included an extensive examination of lithium intercalation compounds. Lithium's low atomic weight and high reducing potential have stimulated this examination. For a material to be considered as an electrode in such a system, it mus...

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Bibliographic Details
Published in:Chemistry of materials 1994-01, Vol.6:1
Main Authors: Clerc, D.G., Cleary, D.A.
Format: Article
Language:English
Subjects:
ABSORPTION
ALKALI METALS
CHALCOGENIDES
COBALT COMPLEXES
COMPLEXES
ELECTROLYTES
ELEMENTS
ENERGY STORAGE
LITHIUM
METALS
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
SOLID ELECTROLYTES
SORPTION
SORPTIVE PROPERTIES
SULFIDES
SULFUR COMPOUNDS
SURFACE PROPERTIES
TIN COMPOUNDS
TRANSITION ELEMENT COMPLEXES 250903 > Energy Storage-- Batteries-- Materials, Components, & Auxiliaries
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Summary:The search for suitable lightweight rechargeable batteries has included an extensive examination of lithium intercalation compounds. Lithium's low atomic weight and high reducing potential have stimulated this examination. For a material to be considered as an electrode in such a system, it must be able to participate in a lithium intercalation reaction. A variety of solid state host lattices satisfy this requirement: TiS[sub 2], Fe[sub 2]P[sub 2]S[sub 6], and V[sub 2]O[sub 5] to name but a few. In this communication the authors report the lithium intercalation into SnS[sub 2](CoCp[sub 2])[sub x]. This is a significant observation because, in the material, the charge is transferred not to the host lattice but to a different intercalated species. 15 refs., 1 fig.
ISSN:0897-4756
1520-5002
DOI:10.1021/cm00037a004