Vapor-Liquid Equilibria for Systems of 1-Butanol with 2-Methyl-1-butanol, 3-Methyl-1-butanol, 2-Methyl-2-butanol, and 3-Methyl-2-butanol at 30 and 100 kPa

Vapor-liquid equilibrium data were measured for binary systems of 1-butanol with 2-methyl-1-butanol, 3-methyl-1-butanol, 2-methyl-2-butanol, and 3-methyl-2-butanol at 30 and 100 kPa. The experimental data obtained in this work are thermodynamically consistent according to a point-to-point consistenc...

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Bibliographic Details
Published in:Journal of chemical and engineering data 1994-04, Vol.39 (2), p.271-274
Main Authors: Aucejo, Antonio, Burguet, M. Cruz, Monton, Juan B, Munoz, Rosa, Sanchotello, Margarita, Vazquez, M. Isabel
Format: Article
Language:English
Subjects:
10 SYNTHETIC FUELS
100300 - Synthetic Fuels- Properties & Composition- (1990-)
400201 - Chemical & Physicochemical Properties
ALCOHOLS
BINARY MIXTURES
BOILING POINTS
BUTANOLS
Chemistry
DATA
DENSITY
DESIGN
DISPERSIONS
DISTILLATION EQUIPMENT
Exact sciences and technology
EXPERIMENTAL DATA
General and physical chemistry
HYDROXY COMPOUNDS
INFORMATION
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
Liquid-vapor equilibria
MIXTURES
NUMERICAL DATA
OPTICAL PROPERTIES
ORGANIC COMPOUNDS
Phase equilibria
PHYSICAL PROPERTIES
REFRACTIVE INDEX
THERMODYNAMIC PROPERTIES
TRANSITION TEMPERATURE
VAPOR PRESSURE
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Summary:Vapor-liquid equilibrium data were measured for binary systems of 1-butanol with 2-methyl-1-butanol, 3-methyl-1-butanol, 2-methyl-2-butanol, and 3-methyl-2-butanol at 30 and 100 kPa. The experimental data obtained in this work are thermodynamically consistent according to a point-to-point consistency test, and deviation from ideal behavior is small in all cases. They can be equally well correlated with the Margules, Van Laar, Wilson, NRTL, and UNIQUAC equations.
ISSN:0021-9568
1520-5134
DOI:10.1021/je00014a017