Partial Molar Volumes of Uni-univalent Electrolytes in Methanol + Water. 1. Lithium Chloride, Sodium Chloride, and Potassium Chloride

Densities of methanol + water + lithium chloride, + sodium chloride, and + potassium chloride were measured at 15, 25, 35, and 45 C. The apparent molar volumes of the electrolytes in these mixtures were calculated, and the apparent molar volumes at infinite dilution, the partial molar volumes, and p...

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Bibliographic Details
Published in:Journal of chemical and engineering data 1994-04, Vol.39 (2), p.207-213
Main Authors: Takenaka, Nobuo, Takemura, Takeshi, Sakurai, Masao
Format: Article
Language:English
Subjects:
400201 - Chemical & Physicochemical Properties
ALCOHOLS
ALKALI METAL COMPOUNDS
CHLORIDES
CHLORINE COMPOUNDS
DATA
DENSITY
DISPERSIONS
EXPANSION
EXPERIMENTAL DATA
HALIDES
HALOGEN COMPOUNDS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
INFORMATION
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
LITHIUM CHLORIDES
LITHIUM COMPOUNDS
LITHIUM HALIDES
METHANOL
MIXTURES
NUMERICAL DATA
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
POTASSIUM CHLORIDES
POTASSIUM COMPOUNDS
SODIUM CHLORIDES
SODIUM COMPOUNDS
SOLVENT PROPERTIES
THERMAL EXPANSION
THERMODYNAMIC PROPERTIES
WATER
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Description
Summary:Densities of methanol + water + lithium chloride, + sodium chloride, and + potassium chloride were measured at 15, 25, 35, and 45 C. The apparent molar volumes of the electrolytes in these mixtures were calculated, and the apparent molar volumes at infinite dilution, the partial molar volumes, and partial molar thermal expansivities were evaluated.
ISSN:0021-9568
1520-5134
DOI:10.1021/je00014a004