Dissolution of Columbia River Basalt under mildly acidic conditions as a function of temperature: Experimental results relevant to the geological sequestration of carbon dioxide

• Published in: Applied geochemistry 2009-05, Vol.24 (5), p.980-987
• Main Authors: Todd Schaef, H., Peter McGrail, B.
• Format: Article
• Language: English
• Subjects: ACTIVATION ENERGY; ANAEROBIC CONDITIONS; BASALT; CARBON DIOXIDE; CARBONATE MINERALS; CARBONATES; CLIMATIC CHANGE; COLUMBIA RIVER; DISSOLUTION; Earth sciences; Earth, ocean, space; Engineering and environment geology. Geothermics; ENVIRONMENTAL SCIENCES; Exact sciences and technology; Freshwater; Geochemistry; GEOSCIENCES; KINETICS; Pollution, environment geology; REACTION KINETICS; SIMULATION; STABILITY
• ISSN: 0883-2927; 1872-9134
• DOI: 10.1016/j.apgeochem.2009.02.025

Increasing attention is being focused on the rapid rise of CO 2 levels in the atmosphere, which many believe to be the major contributing factor to global climate change. Sequestering CO 2 in deep geological formations has been proposed as a long-term solution to help stabilize CO 2 levels. However, before such technology can be developed and implemented, a basic understanding of H 2O–CO 2 systems and the chemical interactions of these fluids with the host formation must be obtained. Important issues concerning mineral stability, reaction rates, and carbonate formation are all controlled or at least significantly impacted by the kinetics of rock–water reactions in mildly acidic, CO 2-saturated solutions. Basalt has recently been identified as a potentially important host formation for geological sequestration. Dissolution kinetics of the Columbia River Basalt (CRB) were measured for a range of temperatures (25–90 °C) under mildly acidic to neutral pH conditions using the single-pass flow-through test method. Under anaerobic conditions, the normalized dissolution rates for CRB decrease with increasing pH (3 ⩽ pH ⩽ 7) with a slope, η, of −0.15 ± 0.01. Activation energy, E a, has been estimated at 32.0 ± 2.4 kJ mol −1. Dissolution kinetics measurements like these are essential for modeling the rate at which CO 2-saturated fluids react with basalt and ultimately drive conversion rates to carbonate minerals in situ.