Well-defined NHC–Pd(II)–Im (NHC= N-heterocyclic carbene; Im=1-methylimidazole) complexes catalyzed amination of aryl chlorides

A new class of well-defined NHC–Pd(II)–Im complexes was synthesized and was found to be an efficient catalyst for the amination reactions of aryl chlorides. Under the optimal reaction conditions, a range of amines can be coupled to give the amination products in good to high yields. [Display omitted...

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Bibliographic Details
Published in:Tetrahedron 2011-07, Vol.67 (29), p.5150-5155
Main Authors: Zhu, Lei, Gao, Ting-Ting, Shao, Li-Xiong
Format: Article
Language:English
Subjects:
Amination reaction
Amines
Aromatic compounds
Carbenes
Catalysis
Catalysts
Catalysts: preparations and properties
chemical reactions
chemical structure
Chemistry
Chlorides
Exact sciences and technology
General and physical chemistry
Heterocyclic compounds
Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings
Imidazole
Joining
N-Heterocyclic carbene
Optimization
Organic chemistry
Palladium complex
Preparations and properties
Synthetic method
Tetrahedrons
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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