Solvent effects on the reactivity of solvated electrons with ammonium and nitrate ions in 1-butanol-water solvents

Values of the rate constants, k 2 (10 6  m 3 mol −1 s −1 ), of solvated electrons, with several related salts, in pure water and pure 1-butanol solvents at 298 K are, respectively, as follows: LiNO 3 , 9.2, 0.19; NH 4 NO 3 , 10, 8.3; NH 4 ClO 4 , 1.5 × 10 −3 , 12 in 20 mol% water; LiClO 4 , 1.0 × 10...

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Bibliographic Details
Published in:Canadian journal of chemistry 1993-09, Vol.71 (9), p.1303-1310
Main Authors: Chen, Ruzhong, Freeman, Gordon R
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
General and physical chemistry
Physical chemistry of induced reactions (with radiations, particles and ultrasonics)
Solvated and trapped electrons
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Summary:Values of the rate constants, k 2 (10 6  m 3 mol −1 s −1 ), of solvated electrons, with several related salts, in pure water and pure 1-butanol solvents at 298 K are, respectively, as follows: LiNO 3 , 9.2, 0.19; NH 4 NO 3 , 10, 8.3; NH 4 ClO 4 , 1.5 × 10 −3 , 12 in 20 mol% water; LiClO 4 , 1.0 × 10 −4 ,
ISSN:0008-4042
1480-3291
DOI:10.1139/v93-168