Catalytic Oxidation of CH3Cl by Cr2O3

The oxidation of CH 3 Cl in air using a commercially available Cr 2 O 3 catalyst was studied in a packed-bed, isothermal reactor in the temperature range of 340-470°C and at I atm. Reaction rates were independent of the concentration of oxygen for CH 3 Cl partial pressures below 0.043 atm. A non-lin...

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Bibliographic Details
Published in:Combustion science and technology 1986-06, Vol.47 (5-6), p.229-237
Main Authors: WELDON, J., SENKAN, S. M.
Format: Article
Language:English
Subjects:
Applied sciences
Combustion of gaseous fuels
Combustion. Flame
Energy
Energy. Thermal use of fuels
Exact sciences and technology
Theoretical studies. Data and constants. Metering
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Summary:The oxidation of CH 3 Cl in air using a commercially available Cr 2 O 3 catalyst was studied in a packed-bed, isothermal reactor in the temperature range of 340-470°C and at I atm. Reaction rates were independent of the concentration of oxygen for CH 3 Cl partial pressures below 0.043 atm. A non-linear second order rate model was satisfactory in correlating the data.
ISSN:0010-2202
1563-521X
DOI:10.1080/00102208608923875