Strongly coupled binuclear uranium–oxo complexes from uranyl oxo rearrangement and reductive silylation

The most common motif in uranium chemistry is the d 0 f 0 uranyl ion [UO 2 ] 2+ in which the oxo groups are rigorously linear and inert. Alternative geometries, such as the cis -uranyl, have been identified theoretically and implicated in oxo-atom transfer reactions that are relevant to environmenta...

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Bibliographic Details
Published in:Nature chemistry 2012-03, Vol.4 (3), p.221-227
Main Authors: Arnold, Polly L., Jones, Guy M., Odoh, Samuel O., Schreckenbach, Georg, Magnani, Nicola, Love, Jason B.
Format: Article
Language:English
Subjects:
639/638/263
639/638/549
Analytical Chemistry
Biochemistry
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Inorganic Chemistry
Insect migration
Ligands
Magnetic properties
Organic Chemistry
Physical Chemistry
Radioactive wastes
Remediation
Retention
Speciation
Uranium
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