Cr3+-Mediated Addition of Arylzincs to Aldehydes

Addition of arylzincs to aldehydes was achieved by making use of the novel transmetallation of arylzincs into Cr3+ compounds. Various α-substituted benzyl alcohols or 3-substituted 1(3H)-isobenzofuranones, containing reactive functional groups, were synthesized in good yields. Me3SiCl exerted benefi...

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Published in:Chemistry letters 1996-12, Vol.25 (12), p.1069-1070
Main Authors: Ogawa, Yoshihiro, Mori, Mitsuo, Saiga, Akihiro, Takagi, Kentaro
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Language:English
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description Addition of arylzincs to aldehydes was achieved by making use of the novel transmetallation of arylzincs into Cr3+ compounds. Various α-substituted benzyl alcohols or 3-substituted 1(3H)-isobenzofuranones, containing reactive functional groups, were synthesized in good yields. Me3SiCl exerted beneficial effects on the reaction.
doi_str_mv 10.1246/cl.1996.1069
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title Cr3+-Mediated Addition of Arylzincs to Aldehydes
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