Synthesis and Properties of the Derivatives of 2,4,6-Tris(Phenoxy)-1,3,5-Triazine

Five derivatives of 2,4,6-tris(phenoxy)-1,3,5-triazine were synthesized and characterized by 1 H NMR, IR and mass spectrometries. The optical and electrochemical properties of the synthesized compounds were studied. Dilute solutions of 1,3,5-triazines compounds in acetonitrile absorb electromagnetic...

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Published in:Molecular Crystals and Liquid Crystals 2014-02, Vol.590 (1), p.73-79
Main Authors: Dainyte, Aiste, Gudeika, Dalius, Buika, Gintaras, Grazulevicius, Juozas Vidas
Format: Article
Language:English
Subjects:
Acetonitrile
band gap
Chemical compounds
Chemical synthesis
Crystals
cyclic voltammetry
Derivatives
Electrons
Energy gaps (solid state)
Infrared radiation
Liquid crystals
Mass spectrometry
Optical properties
Radiation
spectrometry
substituted 1,3,5-triazine
Voltammetry
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description Five derivatives of 2,4,6-tris(phenoxy)-1,3,5-triazine were synthesized and characterized by 1 H NMR, IR and mass spectrometries. The optical and electrochemical properties of the synthesized compounds were studied. Dilute solutions of 1,3,5-triazines compounds in acetonitrile absorb electromagnetic radiation in the region of 200-400 nm with the band gaps of 3.96-4.58 eV. Cyclic voltammetry studies revealed that the electron affinities of the synthesized compound range from −3.24 eV to −3.58 eV, and solid state ionization potentials range from 7.20 eV to 8.16 eV.
doi_str_mv 10.1080/15421406.2013.873850
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1563-5287
1527-1943
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source EBSCOhost MLA International Bibliography With Full Text; Taylor and Francis Science and Technology Collection
subjects Acetonitrile
band gap
Chemical compounds
Chemical synthesis
Crystals
cyclic voltammetry
Derivatives
Electrons
Energy gaps (solid state)
Infrared radiation
Liquid crystals
Mass spectrometry
Optical properties
Radiation
spectrometry
substituted 1,3,5-triazine
Voltammetry
title Synthesis and Properties of the Derivatives of 2,4,6-Tris(Phenoxy)-1,3,5-Triazine
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