Water Molecules in Hydrotalcite-like Layered Double Hydroxides: Interplay between the Hydration of the Anions and the Metal Hydroxide Layer

• Published in: Zeitschrift für anorganische und allgemeine Chemie (1950) 2015-04, Vol.641 (5), p.927-934
• Main Authors: Marappa, Shivanna, Vishnu Kamath, P.
• Format: Article
• Language: English
• Subjects: Aluminum; Anionic clays; Hydration; Layered compounds; Magnesium
• ISSN: 0044-2313; 1521-3749
• DOI: 10.1002/zaac.201500065

Layered double hydroxides comprise positively charged metal hydroxide layers and intercalated anions. These materials are obtained from aqueous medium both in nature and in the laboratory. Consequently the layered double hydroxides include a considerable amount of water. The presented study was designed to determine the proportion of water associated with the hydration sphere of the anion as opposed to that of the metal hydroxide slab. Among the two differently bound water species observed in all layered double hydroxides, the weakly bound water is associated with the metal hydroxide layer and is lost at 100 °C, whereas the strongly bound water is in the hydration sphere of the anion and is lost at higher temperatures (100 °C ≤ T ≤ 250 °C). This is in contrast to the better known cationic clays, wherein all the intercalated water is generally found to be in the hydration sphere of the cations. Further the water molecules in layered double hydroxides also bond to each other, leading to the incorporation of water in excess of what is predicted by the Miyata formula (Miyata, 1975) based on crystal chemical considerations. The excess water is one of the reasons for the poor crystallinity of layered hydroxides.