Phase relations of phlogopite and pyroxene with magnesite from 4 to 8 GPa: KCMAS–H2O and KCMAS–H2O–CO2

• Published in: Contributions to mineralogy and petrology 2016-11, Vol.171 (11), p.1, Article 88
• Main Authors: Enggist, Andreas, Luth, Robert W.
• Format: Article
• Language: English
• Subjects: Carbon dioxide; Earth and Environmental Science; Earth Sciences; Geology; Melting; Mineral Resources; Mineralogy; Original Paper; Petrology; Phase transitions
• ISSN: 0010-7999; 1432-0967
• DOI: 10.1007/s00410-016-1304-2

To constrain the melting phase relationships of phlogopite and magnesite in the presence of clino- and orthopyroxene, we performed experiments in the K 2 O–CaO–MgO–Al 2 O 3 –SiO 2 –H 2 O (KCMAS–H 2 O) and K 2 O–CaO–MgO–Al 2 O 3 –SiO 2 –H 2 O–CO 2 (KCMAS–H 2 O–CO 2 ) systems at pressures of 4–8 GPa and temperatures from 1100 to 1600 °C. We bracketed the carbonate-free solidus between 1250 and 1300 °C at 4 and 5 GPa, and between 1300 and 1350 °C at 6, 7 and 8 GPa. The carbonate-bearing solidus was bracketed between 1150 and 1200 °C at 4, 5 and 6 GPa, and between 1100 and 1150 °C at 7 and 8 GPa. Below the solidus in both systems at 4–6 GPa, phlogopite is in equilibrium with enstatite, diopside, garnet (plus magnesite in the carbonate-bearing system) and a fluid. At 7 GPa, phlogopite coexists with KK-richterite, enstatite, diopside, garnet (plus magnesite in the carbonate-bearing system) and a fluid. KK-richterite is the only stable K-bearing phase at 8 GPa and coexists with enstatite, diopside, garnet (plus magnesite in the carbonate-bearing system) and a fluid. In KCMAS–H 2 O, phlogopite is present to ~100 °C above the solidus. Olivine forms at the solidus and coexists with enstatite, diopside, garnet and melt. At depth in a subcontinental lithospheric mantle keel, phlogopite would be stable with orthopyroxene, clinopyroxene and magnesite to ~5 GPa along a 40 mW/m 2 geotherm. A hydrous, potassic and CO 2 -bearing melt that intrudes the subcontinental mantle can react with olivine, enstatite and garnet, crystallizing phlogopite, magnesite and potentially liberating a hydrous fluid.