Physicochemical properties of ionic liquid mixtures containing choline chloride, chromium (III) chloride and water: effects of temperature and water content

• Published in: Ionics 2017-03, Vol.23 (3), p.637-643
• Main Authors: Protsenko, V. S., Bobrova, L. S., Danilov, F. I.
• Format: Article
• Language: English
• Subjects: Chemistry; Chemistry and Materials Science; Chloride; Chlorides; Choline; Condensed Matter Physics; Density; Electrical resistivity; Electrochemistry; Energy Storage; Hole size; Ionic liquids; Ionic mobility; Ions; Moisture content; Optical and Electronic Materials; Original Paper; Renewable and Green Energy; Room temperature; Surface tension; Temperature effects; Trivalent chromium; Viscosity; Viscous flow
• ISSN: 0947-7047; 1862-0760
• DOI: 10.1007/s11581-016-1826-7

The effects of water addition and temperature on some physicochemical properties of room temperature ionic liquids containing chromium chloride, choline chloride and water in the molar ratio of 1:2.5: x (where x  = 6, 9, 12, 15 or 18) have been studied. The density, viscosity, surface tension and conductivity of the liquid mixtures were measured for the temperature range of 25 to 80 °C. Increasing both water content and temperature resulted in decreasing density, surface tension and viscosity and increasing electrical conductivity. The average void radii (hole sizes) for the liquid systems under study were calculated; they were in the range of 1.21 to 1.82 Å. The average hole size was stated to grow with increasing both temperature and water content in the mixture. The variation of the average void radii correlates with the change in viscosity and conductivity. The activation energies of viscous flow and conductivity diminishes with increasing water content in the liquid mixture. There is a strong linear correlation between conductivity and fluidity which indicates that the conductivity of the ionic liquid mixtures is generally controlled by the ionic mobility. A moderate viscosity and higher conductivity of the Cr(III)-containing ionic liquids with extra-water addition (at x  > 9) make them suitable for the development of chromium electrodeposition processes.