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Crystal structures, thermal properties, and luminescent properties of two novel mononuclear lanthanide complexes with 2,4-dichlorobenzoic acid and 2,2′:6′,2″-terpyridine
Two novel mononuclear lanthanide complexes, [Ln(2,4-DClBA) 3 (terpy)(H 2 O)]·H 2 O (Ln = Dy(1), Er(2)); 2,4-DClBA: 2,4-dichlorobenzoate; terpy: 2,2′:6′,2″-terpyridine; have been synthesized and characterized by single-crystal and powder X-ray diffraction. The results reveal that complexes 1–2 are is...
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| Published in: | Journal of thermal analysis and calorimetry 2016-12, Vol.126 (3), p.1703-1712 |
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| Main Authors: | , , , , , |
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| cited_by | cdi_FETCH-LOGICAL-c389t-92694594806faf0dee39590d5e6fd34eb3ee0c48227133b35a1632c1061c2b563 |
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| cites | cdi_FETCH-LOGICAL-c389t-92694594806faf0dee39590d5e6fd34eb3ee0c48227133b35a1632c1061c2b563 |
| container_end_page | 1712 |
| container_issue | 3 |
| container_start_page | 1703 |
| container_title | Journal of thermal analysis and calorimetry |
| container_volume | 126 |
| creator | Wang, Ye Zhao, Qing-Qing Ren, Ning Zhang, Jian-Jun Geng, Li-Na Wang, Shu-Ping |
| description | Two novel mononuclear lanthanide complexes, [Ln(2,4-DClBA)
3
(terpy)(H
2
O)]·H
2
O (Ln = Dy(1), Er(2)); 2,4-DClBA: 2,4-dichlorobenzoate; terpy: 2,2′:6′,2″-terpyridine; have been synthesized and characterized by single-crystal and powder X-ray diffraction. The results reveal that complexes 1–2 are isomorphous, and each Ln
3+
ion is nine coordinated adopting a distorted monocapped square antiprismatic molecular geometry. Mononuclear complexes 1–2 are stitched together via Cl–
π
and hydrogen bonding interactions to form the 1D, 2D, 3D supramolecular structures, which the 3D is rarely observed. Thermal decomposition mechanism is determined by TG/DSC-FTIR, and the 3D stacked plots for the FTIR spectra of the evolved gases were recorded. Heat capacities of complexes 1–2 were measured, and the derived thermodynamic functions (
H
T
−
H
298.15
), (
S
T
−
S
298.15
) and (
G
T
−
G
298.15
) of the complexes relative to the standard reference temperature 298.15 K were obtained. The activation energy
E
values of the first decomposition stage for title complexes were calculated by integral isoconversional nonlinear (NL-INT) and Starink methods. Complex 1 shows the characteristic emission of Dy
3+
with strong yellow emission. |
| doi_str_mv | 10.1007/s10973-016-5728-8 |
| format | article |
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3
(terpy)(H
2
O)]·H
2
O (Ln = Dy(1), Er(2)); 2,4-DClBA: 2,4-dichlorobenzoate; terpy: 2,2′:6′,2″-terpyridine; have been synthesized and characterized by single-crystal and powder X-ray diffraction. The results reveal that complexes 1–2 are isomorphous, and each Ln
3+
ion is nine coordinated adopting a distorted monocapped square antiprismatic molecular geometry. Mononuclear complexes 1–2 are stitched together via Cl–
π
and hydrogen bonding interactions to form the 1D, 2D, 3D supramolecular structures, which the 3D is rarely observed. Thermal decomposition mechanism is determined by TG/DSC-FTIR, and the 3D stacked plots for the FTIR spectra of the evolved gases were recorded. Heat capacities of complexes 1–2 were measured, and the derived thermodynamic functions (
H
T
−
H
298.15
), (
S
T
−
S
298.15
) and (
G
T
−
G
298.15
) of the complexes relative to the standard reference temperature 298.15 K were obtained. The activation energy
E
values of the first decomposition stage for title complexes were calculated by integral isoconversional nonlinear (NL-INT) and Starink methods. Complex 1 shows the characteristic emission of Dy
3+
with strong yellow emission.</description><identifier>ISSN: 1388-6150</identifier><identifier>EISSN: 1588-2926</identifier><identifier>DOI: 10.1007/s10973-016-5728-8</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Activation energy ; Analysis ; Analytical Chemistry ; Chemistry ; Chemistry and Materials Science ; Crystal structure ; Crystals ; Diffraction ; Hydrogen ; Inorganic Chemistry ; Measurement Science and Instrumentation ; Physical Chemistry ; Polymer Sciences ; Rare earth metals ; Structure ; Thermal decomposition ; Thermal properties ; Thermodynamic properties ; X-rays</subject><ispartof>Journal of thermal analysis and calorimetry, 2016-12, Vol.126 (3), p.1703-1712</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2016</rights><rights>COPYRIGHT 2016 Springer</rights><rights>Copyright Springer Science & Business Media 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c389t-92694594806faf0dee39590d5e6fd34eb3ee0c48227133b35a1632c1061c2b563</citedby><cites>FETCH-LOGICAL-c389t-92694594806faf0dee39590d5e6fd34eb3ee0c48227133b35a1632c1061c2b563</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Wang, Ye</creatorcontrib><creatorcontrib>Zhao, Qing-Qing</creatorcontrib><creatorcontrib>Ren, Ning</creatorcontrib><creatorcontrib>Zhang, Jian-Jun</creatorcontrib><creatorcontrib>Geng, Li-Na</creatorcontrib><creatorcontrib>Wang, Shu-Ping</creatorcontrib><title>Crystal structures, thermal properties, and luminescent properties of two novel mononuclear lanthanide complexes with 2,4-dichlorobenzoic acid and 2,2′:6′,2″-terpyridine</title><title>Journal of thermal analysis and calorimetry</title><addtitle>J Therm Anal Calorim</addtitle><description>Two novel mononuclear lanthanide complexes, [Ln(2,4-DClBA)
3
(terpy)(H
2
O)]·H
2
O (Ln = Dy(1), Er(2)); 2,4-DClBA: 2,4-dichlorobenzoate; terpy: 2,2′:6′,2″-terpyridine; have been synthesized and characterized by single-crystal and powder X-ray diffraction. The results reveal that complexes 1–2 are isomorphous, and each Ln
3+
ion is nine coordinated adopting a distorted monocapped square antiprismatic molecular geometry. Mononuclear complexes 1–2 are stitched together via Cl–
π
and hydrogen bonding interactions to form the 1D, 2D, 3D supramolecular structures, which the 3D is rarely observed. Thermal decomposition mechanism is determined by TG/DSC-FTIR, and the 3D stacked plots for the FTIR spectra of the evolved gases were recorded. Heat capacities of complexes 1–2 were measured, and the derived thermodynamic functions (
H
T
−
H
298.15
), (
S
T
−
S
298.15
) and (
G
T
−
G
298.15
) of the complexes relative to the standard reference temperature 298.15 K were obtained. The activation energy
E
values of the first decomposition stage for title complexes were calculated by integral isoconversional nonlinear (NL-INT) and Starink methods. Complex 1 shows the characteristic emission of Dy
3+
with strong yellow emission.</description><subject>Activation energy</subject><subject>Analysis</subject><subject>Analytical Chemistry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>Crystals</subject><subject>Diffraction</subject><subject>Hydrogen</subject><subject>Inorganic Chemistry</subject><subject>Measurement Science and Instrumentation</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Rare earth metals</subject><subject>Structure</subject><subject>Thermal decomposition</subject><subject>Thermal properties</subject><subject>Thermodynamic properties</subject><subject>X-rays</subject><issn>1388-6150</issn><issn>1588-2926</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1kc2KFDEUhQtRcBx9AHcBV0LXeJNUpRJ3Q-PPwIDgzzqkU7e6M1QlbZKamXblGwn6Rj6JacvFzEICyeHmO7m5nKp6TuGMAnSvEgXV8RqoqNuOyVo-qE5oK2XNFBMPi-ZFC9rC4-pJSlcAoBTQk-rHOh5SNiNJOc42zxHTiuQdxqnU9jHsMWZ3rBnfk3GenMdk0ec7dyQMJN8E4sM1jmQKPvjZjmgiGY3PO-Ndj8SGaT_ibaFvXN4Rtmrq3tndGGLYoP8WnCXGuv5vG7Ziv7__fC3KdlS_6oxxf4iuL82fVo8GMyZ89u88rb68ffN5_b6-_PDuYn1-WVsuVa7L0KppVSNBDGaAHpGrVkHfohh63uCGI4JtJGMd5XzDW0MFZ5aCoJZtWsFPqxfLu2XOrzOmrK_CHH1pqamUIBvasaZQZwu1NSNq54eQo7Fl9Tg5GzwOrtTPmw4ENIp1xfDynqEwGW_z1swp6YtPH--zdGFtDClFHPQ-usnEg6agj6HrJXRdQtfH0LUsHrZ4UmH9FuOdb__X9AeILLOo</recordid><startdate>20161201</startdate><enddate>20161201</enddate><creator>Wang, Ye</creator><creator>Zhao, Qing-Qing</creator><creator>Ren, Ning</creator><creator>Zhang, Jian-Jun</creator><creator>Geng, Li-Na</creator><creator>Wang, Shu-Ping</creator><general>Springer Netherlands</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope></search><sort><creationdate>20161201</creationdate><title>Crystal structures, thermal properties, and luminescent properties of two novel mononuclear lanthanide complexes with 2,4-dichlorobenzoic acid and 2,2′:6′,2″-terpyridine</title><author>Wang, Ye ; Zhao, Qing-Qing ; Ren, Ning ; Zhang, Jian-Jun ; Geng, Li-Na ; Wang, Shu-Ping</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c389t-92694594806faf0dee39590d5e6fd34eb3ee0c48227133b35a1632c1061c2b563</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Activation energy</topic><topic>Analysis</topic><topic>Analytical Chemistry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>Crystals</topic><topic>Diffraction</topic><topic>Hydrogen</topic><topic>Inorganic Chemistry</topic><topic>Measurement Science and Instrumentation</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Rare earth metals</topic><topic>Structure</topic><topic>Thermal decomposition</topic><topic>Thermal properties</topic><topic>Thermodynamic properties</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Ye</creatorcontrib><creatorcontrib>Zhao, Qing-Qing</creatorcontrib><creatorcontrib>Ren, Ning</creatorcontrib><creatorcontrib>Zhang, Jian-Jun</creatorcontrib><creatorcontrib>Geng, Li-Na</creatorcontrib><creatorcontrib>Wang, Shu-Ping</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of thermal analysis and calorimetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Ye</au><au>Zhao, Qing-Qing</au><au>Ren, Ning</au><au>Zhang, Jian-Jun</au><au>Geng, Li-Na</au><au>Wang, Shu-Ping</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal structures, thermal properties, and luminescent properties of two novel mononuclear lanthanide complexes with 2,4-dichlorobenzoic acid and 2,2′:6′,2″-terpyridine</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><stitle>J Therm Anal Calorim</stitle><date>2016-12-01</date><risdate>2016</risdate><volume>126</volume><issue>3</issue><spage>1703</spage><epage>1712</epage><pages>1703-1712</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><abstract>Two novel mononuclear lanthanide complexes, [Ln(2,4-DClBA)
3
(terpy)(H
2
O)]·H
2
O (Ln = Dy(1), Er(2)); 2,4-DClBA: 2,4-dichlorobenzoate; terpy: 2,2′:6′,2″-terpyridine; have been synthesized and characterized by single-crystal and powder X-ray diffraction. The results reveal that complexes 1–2 are isomorphous, and each Ln
3+
ion is nine coordinated adopting a distorted monocapped square antiprismatic molecular geometry. Mononuclear complexes 1–2 are stitched together via Cl–
π
and hydrogen bonding interactions to form the 1D, 2D, 3D supramolecular structures, which the 3D is rarely observed. Thermal decomposition mechanism is determined by TG/DSC-FTIR, and the 3D stacked plots for the FTIR spectra of the evolved gases were recorded. Heat capacities of complexes 1–2 were measured, and the derived thermodynamic functions (
H
T
−
H
298.15
), (
S
T
−
S
298.15
) and (
G
T
−
G
298.15
) of the complexes relative to the standard reference temperature 298.15 K were obtained. The activation energy
E
values of the first decomposition stage for title complexes were calculated by integral isoconversional nonlinear (NL-INT) and Starink methods. Complex 1 shows the characteristic emission of Dy
3+
with strong yellow emission.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10973-016-5728-8</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1388-6150 |
| ispartof | Journal of thermal analysis and calorimetry, 2016-12, Vol.126 (3), p.1703-1712 |
| issn | 1388-6150 1588-2926 |
| language | eng |
| recordid | cdi_proquest_journals_1880841724 |
| source | Springer Nature |
| subjects | Activation energy Analysis Analytical Chemistry Chemistry Chemistry and Materials Science Crystal structure Crystals Diffraction Hydrogen Inorganic Chemistry Measurement Science and Instrumentation Physical Chemistry Polymer Sciences Rare earth metals Structure Thermal decomposition Thermal properties Thermodynamic properties X-rays |
| title | Crystal structures, thermal properties, and luminescent properties of two novel mononuclear lanthanide complexes with 2,4-dichlorobenzoic acid and 2,2′:6′,2″-terpyridine |
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