Prediction of Gas Solubility in Ionic Liquids Using the Cosmo-Sac Model

• Published in: Chemical and Process Engineering 2017-03, Vol.38 (1), p.19-30
• Main Authors: Jaschik, Manfred, Piech, Daniel, Warmuzinski, Krzysztof, Jaschik, Jolanta
• Format: Article
• Language: English
• Subjects: Carbon dioxide; carbon dioxide capture; COSMO-SAC model; Gas solubility; Henry’s constant; Ionic liquids; Numerical prediction; solubility; vapour-liquid equilibrium
• ISSN: 2300-1925; 0208-6425; 2300-1925
• DOI: 10.1515/cpe-2017-0003

Thermodynamic principles for the dissolution of gases in ionic liquids (ILs) and the COSMO-SAC model are presented. Extensive experimental data of Henry’s law constants for CO , N and O in ionic liquids at temperatures of 280-363 K are compared with numerical predictions to evaluate the accuracy of the COSMO-SAC model. It is found that Henry’s law constants for CO are predicted with an average relative deviation of 13%. Both numerical predictions and experimental data reveal that the solubility of carbon dioxide in ILs increases with an increase in the molar mass of ionic liquids, and is visibly more affected by the anion than by the cation. The calculations also show that the highest solubilities are obtained for [Tf N]ˉ. Thus, the model can be regarded as a useful tool for the screening of ILs that offer the most favourable CO solubilities. The predictions of the COSMOSAC model for N and O in ILs differ from the pertinent experimental data. In its present form the COSMO-SAC model is not suitable for the estimation of N and O solubilities in ionic liquids.